学科分类
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1 个结果
  • 简介:TheRamanspectraofthenaturalendmembersofthegarnet-groupminerals,whichincludepyrope,almandineandspessariteofFe-Algarnetseriesandgrossularite,andraditeanduvaroviteofCa-Fegarnetseries,havebeenstrdied.MeasuredRamanspectraofthesemineralsarereasonablyandqualitativelyassignedtotheinternalmodes,translationalandrotatorymodesofSiO4tetrahedra,aswellasthetranslationalmotionofbivalentcationsintheXsite.ThestretchandrotatoryA1gmodesfortheFe-AlgarnetseriesshowobviousRamanshiftsascomparedwiththosefortheCa-Fegarnetseries,owingtothecationsresidingintheXsiteconnectedwithSiO4tetrahedrabysharingthetwoedges.TheRamanshiftsofallmemberswithineitheroftheseriesareattributedmainlytothepropertiesofcationsintheXsitefortheFe-AlgarnetseriesandintheYsitefortheCa-Fegarnetseries.

  • 标签: 拉曼光谱 石榴石 榴子石 铁铝榴石 晶体结构