简介:TheresultsofcommercialapplicationoftwotypesofC_8aromaticsisomerizationcatalystsunderdifferentfeedconditionswerecomparedtogainaninsightinthetechno-economicalbasisforselectingpropertechnologicalrouteattheplant.Thecomparisonrevealsdifferencesineveryaspectoffeedconsumption,unitcapacity,productoutput,productdistribution,andunitprocessparametersdependinguponwhichcatalysttypeisadoptedbytheintegratedPXcomplex.Thetypeofaromaticsisomerizationcatalysthasitsinfluenceontheplantscale,theconstructioncost,theprocessunitcapacityandtheproductcost,withthemagnitudeofitsimpactvaryingwithchangingfeedconditions.
简介:用TSQ-70GC/MS/MS色质仪分析了珠江口盆地100余个原油和生油岩样品,发现部分原油样品具有异常丰富的ααα-C29甾烷(20S)异构体。国内外许多学者认为甾烷ααα-C2920S/(20S+20R)值是最有效的成熟度指标,只与成熟度有关,其热成熟平衡值为0.50-0.55。珠江口盆地有部分油样甾烷ααα-C2920S/(20S+20R)值异常之高,最高达0.67,已超过其热平衡值,已超过了当地成熟、过成熟生油岩样品值。确认油源之后,发现离生油凹陷越远,运移距离越大的原油,其甾烷ααα-C2920S/(20S+20R)值越大。因此,ααα-C2920S(20S+20R)不仅与成熟度有关,还与运移距离有关。
简介:1引言世界上许多中、新生代沉积盆地中均发现丰富的CO2气藏(体积含量大于20%),如松辽盆地[1,2,3]、渤海湾盆地[4]、东海盆地、珠江口盆地和莺歌海盆地[5,6,7]、Pannonian盆地[8,9]、Cooper-Eromanga盆地、北海维京地堑南部[10]、台西南坳陷和日本中新世火山碎屑"绿色凝灰岩"地层[11]及ValVerde前陆盆地[12,13]等,且主要沿环太平洋和欧亚交界、阿尔卑斯和大西洋等构造带分布14,15].研究这些CO2的成因和分布,不仅对天然气勘探和开发有着显著的经济意义,而且对地震预测[14]、壳幔脱气与大气温室效应和环境灾害预测具有重要的理论价值[16].
简介:Thisarticlereferstotheresultsofsmall-scaleandcommercialtestsonhigh-temperaturecrackingofC4fractioninFCCunittoincreasethepropyleneyield.ThebenchtestsrevealedthattheconversionrateofC4fractionduringhigh-temperaturecrackingreached37.38%andpropyleneyieldwasequalto15.60%withtheconversionrateofC4olefinsequatingaround50%.Theresultsofcommercialapplicationshowedthatadoptionofthetechnologyforhigh-temperaturecrackingofC4fractioninFCCunithadledtoanincreaseofpropyleneyieldby2.16%withnoremarkablechangesintheyieldsandpropertiesofotherproducts.
简介:DuringJuneandJuly2003,JingmenPetrochemicalCompanycardedoutthecommercialtestontechnologyforhigh-temperaturecrackingofC5fractiontodecreaseolefincontentofgasolineinDCCU.ThetestresultsshowedthattheolefincontentofDCCgasolinehaddecreasedfrom68.32m%to42.5m%,meanwhilethepropyleneyieldincreasedby0.90m%.
简介:炼油事业部目前正在着手解决重一C6分离装置压降上升问题,以实现装置的安全稳定运行。5月份,重一操作人员在监测时发现,C6分离装置反应系统压降明显上升。技术人员经过分析认定,原料烯烃含量较高,提高反应温度后反应器床层上部瓷球、催化剂结焦导致反应器压降上升。另外,目前使用的MH-508催化剂不能适应反应状况,也是导致反应器压降上升的原因之一。为了确保生产稳定,装置操作人员通过精心调节,设定原料烯烃含量指标,修改反应温度指标,更新氢压机,使装置的反应压降明显降低。为了进一步降低反应压降,事业部决定于近期启用HDO-18催化剂。该催化剂是一种低温催化剂,已经在燕山、茂名石化公司使用,证明可使C6分离装置的反应温度下降,并确保产品质量达到特定企业指标。
简介:ThepolycrystallinephaseWO3/g-C3N4wassynthesizedunderstirringusingtungstenicacid(H2WO4)andgraphiticcarbonnitride(g-C3N4)asrawmaterials.ThecatalystwascharacterizedbyX-raydiffraction(XRD),scanningelectronmicroscopy(SEM),energydispersivespectroscopy(EDS),theFouriertransforminfraredspectroscopy(FT-IR),andtheBrunauer-Emmett-Telleranalysis(BET).ThepolycrystallinephaseWO3/g-C3N4wasdeterminedbyXRDtechnique.TheoxidativedesulfurizationprocesswasinvestigatedusingWO3/g-C3N4asthecatalyst,30%hydrogenperoxide(H202)astheoxidant,and1-butyl-3-methylimidazoliumtetrafluoroborate([bmim]BF4)ionicliquids(ILs)astheextractant.Theoperatingconditions,includingH2WO4amount,ILdose,H2O2volume,temperature,catalystdosage,andtypesofsulfurcompounds,weresystematicallyresearched.Thedesulfurizationratecouldreach98.46%forremovingdibenzothiophene(DBT)fromthemodeloilunderoptimalreactionconditions.Inaddition,thecatalyticactivitywasslightlydecreasedafterfiverecyclesofcatalysts.Thereactionkineticsanalysisshowsthattheoxidativedesulfurizationsystemwasinaccordwiththefirst-orderreactionkineticsequation.Themechanismofoxidativedesulfurizationwasproposed.