简介:ThesubmicronpowdermixturesofTiC-TiN-WC-Mo-C-Nisinteredat1400℃orbelowinvacuumwerestudiedbyX-raydiffraction(XRD),scanningelectronmicroscopy(SEM)andtransmissionelectronmicroscopy(TEM)analyses.TheresultsshowedthatMo2Cformedat800℃orbelow.BothWCandMo2Cdisappearedat1200℃,andTiNdisappearedat1250℃.Inaddition,thevariationsoflatticeconstantsofthetitaniumcarbonitrideandnickelbinderphasewithsinteringtemperaturewereexperimentallyobtained,andthereasonwasanalyzed.
简介:Anewhardfacingprocess,reactivebrazecoatingprocess(RBCC)wasstudied,and(TiC+Cr3C2)/FecompositecoatingswerepreparedbyRBCCusingcarbon,Cr3C2,iron,ferrochromiumandtitaniumpowderastherawmaterialsinvacuumbrazefurnace.TheresultsshowthatTiCisin-situsynthesizedinthecoatings.ThemethodsofintroducingCr3C2havegreateffectsonthedistributionofTiC.AddingCr3C2directlytotherawmaterialsforcoatings,fineTiCparticlesaggregateintodiscoidsparalleltothecoatingsurface,whereas,in-situsynthesizingCr3C2incoatings,theaggregationsofTiCarelumpish.Duringbrazecoating,Cr3C2particlesdirectlyaddeddissolveandprecipitatetobecomeneedle-shaped.Thecoatingshaveanevenandsmoothsurfaceandarecombinedwiththeirmildsteelsubstratesbyametallurgicalbonding.
简介:Basedonalargeamountofdissectionatweldedinterfaceandquantitativemicroscopicexaminationofweldedrate,thesuitablelimitgreyscalevaluewasdetermined,andtheweldedrateofsuperplasticsolid-stateweldinginterfaceofheterogeneoussteelwassystematicallystudiedbymeansofself-madeultrasonicC-scanningimaginginspectionsystem.Theexperimentalresultsshow:theweldedstateofsuperplasticsolid-stateweldinginterfaceofheterogeneoussteelcanbeconductedtobemoreaccurately,reliablyandquicklyinspectedbymeansofthissystem,andtheultrasonictestingresultsaregoodconsistentwithactualexaminationresultsoftheinterfacedefectivedistribution.Withintheextentofthesuitbleweldedrate,theweldedratein40Cr/T10Asuperplasticweldingprocesstestedbythissystemislinearwithitstensilestrengthofjoint.
简介:EffectsofalloyelementsonthemicrostructureandcrackresistanceofFe-C-Crweldsurfacinglayerwereinvestigated.Theresultsshowthatmicrostructuresofthelayermainlyconsistofcarbidesandaustenitematrix.IncreasingCandCrcontentsimpairthecrackresistanceofthelayerduetoincreasedamountofbrittlecarbides.TheadditionofNi,NborMoimprovesthecrackresistanceofFe-C-CrweldsurfacinglayerbyincreasingtheamountofausteniteandformingfineNbCorM7C3carbidesinthelayer.But,theexcessiveNb(>2.50wt%)orMo(>1.88wt%)impairsthecrackresistanceofthelayer,whichhasrelationwithincreasedcarbidesorcarbidecoarseningandaustenitematrixsolidsolutionstrengthening.ThepropercombinationofC,Cr,Ni,NbandMocanfurtherimprovenotonlythecrackresistanceofFe-C-CrweldsurfacinglayerbutalsotheerosionresistanceasaresultoffineNbCandM7C3carbidesdistributinguniformlyinaustenitematrix.Theoptimallayercompositionsare3.05wt%C,20.58wt%Cr,1.75wt%Ni,2.00wt%Nband1.88wt%Mo.
简介:1IntroductionTherareearthcobaltalloyshavethepotentialformakingthemagneticandmagnetoopticalmaterials.Sofar,therareearthcobaltalloyfilmsaresubstantiallyproducedbysputteringorvacuumplating.Ifsuchfilmsarepreparedbyelectrodepositioninstead,productionefficiencywouldbeimprovedandthecompositionofthealloycouldbecontrolled.Becausetheoxidationreductionpotentialsofrareearthelementsareverynegative,organicsolventsmaybeusedaselectrolyticmedia.ElectrodepositionofGdCoandSmCoinorganicsolutionshasbeenreporte...
简介:作为材料的重要性质之一,硬度一直受到人们广泛的重视和研究。Cohen和Liu利用第一性原理计算从理论上预言了一种超硬性能的新材料β—C3N4,其体积弹性模量超过金刚石。CVO3组采用微波等离子体化学气相沉积法(MPCVD),用高纯N2(99.999%)和CH4(99.9%)作反应气体,在单晶Si(100)和多晶Pt衬底上沉积碳氮薄膜,开展了对β-C3N4薄膜的制备与表征的探索性研究,取得了一定的进展。