简介:Reducingthemanufacturingcostofsolarcellsisnecessarytotheirindustrialproduction.Electrodepositingisaneffective,non-vacuummethodwhichisverysuitableforcuttingthemanufacturingcostofthinfilmsaswellasdevelopingitslarge-scaleindustrialproduction.Inthisstudy,about1-μm-thickCu(In,Ga)Se_2(CIGS)precursorswereelectrodepositedonMo/glasssubstratesinaqueoussolutionutilizingathree-electrodepotentiostaticsystem.Triethanolaminewasusedascomplexingagent,andallparametersofelectrodepositionwerepreciselycontrolled.Afterthat,theelectrodepositedprecursorswereselenizedinaSeatmospherewithdifferentheatingramprates(60and600℃·min~(-1)).High-qualityCIGSfilmswereobtained,andtheircharacteristicswereinvestigatedbyX-rayfluorescence,scanningelectronmicroscopy,energydispersivespectroscopy,X-raydiffraction,Ramanspectraandnear-infrared-visible(NIR-Vis)spectra.Theresultsrevealthattherearemanydifferencesbetweenthepropertiesofthefilmsunderdifferentheatingrates.Finally,CIGSsolarcellswerefabricatedusingafastandaslowheatingrate.Themaximumefficienciesachievedforthefilmsselenizedat60and600℃-min~(-1)are3.15%and0.71%,respectively.
简介:X-raydiffraction(XRD)anddifferentialscanningcalorimetry(DSC)wereemployedtoinvestigatetheinfluenceofNicontentonthecrystallizationofamorphousZr70Cu30-xNix(atomfrationin%)alloys,ExperimentalresultsshowthatwiththeNicontentincreasingtheactivationenergiesforcrystallizationofamorphousZr70Cu30-xNixalloysincreasecorrespondingly,indicatingthatthethermalstabilityisgreatlyimproved.AlltheDSCtracesofamorphousZr70Cu30-xNixalloysexhibittwoexothermicpeaks,suggestingthatthecrystallizationprocessviaadouble-stageticles,whilethesecondonecorrespondstotheprecipitaionofnano-scaleZr2Niphaseandcrystallizationofresidualamporphousphase,ThemechanismonthecrystallizationofamorphousZr70Cu30-xNixalloyswasdiscussed.
简介:Thecreepmechanismofas-castMg-6Al-6Ndalloywasstudied.Thestressexponentforcreepis5.8undertheappliedstressesof50-70MPaat175°C.Theactivationenergyforcreepis189kJ·mol-1undertheappliedstressof70MPaintherangeof150-200°C.Thetruestressexponentandthresholdstressforcreeparecalculatedas4.96and10.2MPa,respectively.Thetruestressexponentindicatesthatitscreepmechanismbelongstothedislocationclimb-controlledcreep,whichisinagreementwiththemicrostructurechangesbeforeandaftercreep.ThehighvalueforstressexponentisattributedtotheinteractionofAl11Nd3phasewithdislocations.Theactivationenergyismorethantheself-diffusionactivationenergyofMg,whichisattributedtotheloadtransfertakingplacefromthematrixtoAl11Nd3phaseduringcreep.
简介:Inthiswork,asimpleandfacileone-potoleylaminesolvothermalsyntheticmethodwasdevelopedtosynthesizeCu_2ZnSnS_4(CZTS)nanocrystals.AndtheCu_2ZnSn(S,Se)_4(CZTSSe)thinfilmswerepreparedbyselenizingCZTSnanocrystals.TheobtainedCZTSnanocrystalsandCZTSSefilmswerestudiedusingX-raydiffraction(XRD),transmissionelectronmicroscopy(TEM),scanningelectronmicroscopy(SEM),energy-dispersiveX-rayspectroscopy(EDX),andultraviolet–visiblespectrophotometer(UV–Vis).TEMresultsshowthatthesphere–likeCZTSnanoparticleswithdiameterbetween12and35nmarepolydispersed.XRDstudiesindicatethatthepreparedCZTSnanocrystalsformkesteritecrystalstructure,andtheCZTSSefilmswithkesteritecrystalstructurearealsoobtainedattheannealingtemperaturesof500and550°C.Inparticularafterannealingat500°Cfor20min,theCZTSSefilmexhibitsasmooth,uniform,crack-free,andlarge-grainedtopographyandpossessesCu-poorandSn-richcomposition.Moreover,itshowsstrongopticalabsorptionfromvisibletonear-infrared(IR)region,anditsopticalbandgap(Eg)isfoundtobeabout1.44eV.
简介:本文从观测常规产品Ni70Mn25Co5触媒合金片的表面缺陷入手,讨论了触媒片表观质量对金刚石合成效果的影响,从而也为触媒产品质量标准的制定提供了某些参考依据。
简介:"GasTransmittingFromWesttoEastProject"issignificant.Itshouldensuretheweldingqualityandsafetyofpipeline.Thetaskisveryarduoustoguaranteethequalityoftheprojectintheconditionoflongline,complexweatherandgeologyfeatures.Inthispaper,theweldingcoldcrackingsusceptibilityofdomesticX-70pipelinesteeladoptedbytheproject,whichisoneofthemostinterestingquestionsofweldingqualityaboutpetrolpipeline,wasstudiedbymeansofobliqueY-groovecrackingtest.Thecrackratioofsurfaceandsectionwastestedundertheconditionsofdifferentweldingmaterialsandpreheattemperature.TheX-70pipelinesteelhasgoodcrackresistance.Theresearchhasimportantvaluefortheconstructionoflarge-scalepipelineengineeringandtheapplicationofdomesticX-70pipelinesteel.
简介:DD6alloywasbondedbytransientliquidphase(TLP)diffusionbonding.Themaincompositionsoftheinterlayeralloyemployedweresimilartothoseofthebasemetal,DD6,andacertainamountofelementBwasaddedasthemeltingpointdepressant.Theresultsshowthatitisdifficulttoobtainthejointswiththemicrostructurescompletelyhomogeneous.ForthejointTLPdiffusionbondedat1290℃for12h,abouthalfareasofthebeampossessedαγ+γ′microstructure,nearlyidenticalwiththatofthebasemetal,andtheotherlocalareasconsistedofT-solution,borides,etc.Prolongingthebondingtimeto24h,theinhomogeneousareasinthejointreduced,andthejointpropertyimproved.Thejointstress-rupturestrengthat980℃and1100℃reached90%-100%and70%-80%ofthoseofthebasemetalrespectively.