简介:AnewlygrownBaGa4Se7crystalhasbeensynthesizedviatheBridgman-Stockbargertechnique.Thisnewcrystalhasadvantagesofhighnonlinearoptics(NLO)coefficients,highlaserdamagethresholds,andwidetransparentregions.TheBaGa4Se7crystalhasbrightapplicationprospectsasanonlineargainmediuminmid-infraredandterahertzregions.Inthispaper,thecrystallinestructureandsyntheticmethodoftheBaGa4Se7crystalareintroduced.Therefractiveindicesandabsorptioncoefficientsalongthreedielectricaxesbetween0.1THzand1.0THzarealsoobtained.Theterahertzdifferencefrequencygeneration(THz-DFG)characteristicsbasedontheBaGa4Se7crystalinthefrequencyrangeof0.1THzto1.0THzareanalyzedtheoreticallyandthephase-matchingconditionsarecalculated.TheapplicationofBaGa4Se7crystalsinterahertzwavegenerationisalsodiscussed.
简介:WefabricatepolycrystallineCu(In,Ga)Se2(CIGS)filmsolarcellsonpolyimide(PI)substrateattemperatureof450°Cwithsingle-stageprocess,andobtainapoorcrystallizationofCIGSfilmswithseveralsecondaryphasesinit.Forimprovingitfurther,thetwo-stageprocessisadoptedinsteadofthesingle-stageone.AnextraCu-richCIGSlayerwiththethicknessfrom100nmto200nmisgrownonthesubstrate,andthenanotherCu-poorCIGSfilmwiththicknessof1.5-2.0μmisdepositedonit.Withthemodificationoftheevaporationprocess,thegrainsizeofabsorberlayerisincreased,andtheadditionalsecondaryphasesalmostdisappear.Accordingly,theoveralldeviceperformanceisimproved,andtheconversionefficiencyisenhancedbyabout20%.
简介:小分子有铟听氧化物(ITO)的结构的器官的太阳能电池(振荡)/molybdenum三氧化物(MoO3)(5nm)/rubrene(nm)/fullerene(C70)(ynm)/2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline(BCP)(6nm)/aluminum(艾尔)(150nm)被制作。为设备的活跃的层的厚度在细节被调查。结果证明rubrene层和C70层的最佳厚度分别地是30nm和25nm。设备的降级也被调查。,结果显示开电路的电压(Voc)不变化电线走火电流密度(Jsc),用时间连续地填满因素(FF)和功率变换效率(PCE)减少。降级能在周围的扩散并且渗透到活跃材料并且在房间与C70反应被归因于氧,它能导致界面的系列电阻的增加。
简介:Chalcopyrite-typeCuInSe2nanoparticlesaresuccessfullypreparedbyusingIn2Se3nanoparticlesasaprecursorreactedwithcopperchloride(CuCl)solutionviaaphasetransformationprocessinlowtemperature.Thereactiontimeisakeyparameter.Afterthereactiontimeincreasingfrom0.5hto8h,In2Se3andCuClreactwitheachothergraduallyviaphasetransformationintoCuInSe2withoutanyintermediatephase.ThecrystallinestructureandmorphologyoftheCuInSe2nanoparticlesarecharacterizedbyX-raydiffraction(XRD)andfieldemissionscanningelectronmicroscopy(FESEM).ThediameterofCuInSe2nanoparticleswithgooddispersibilityrangesfrom10nmto20nm.ThebandgapoftheCuInSe2nanoparticlesis1.04eVcalculatedfromtheultraviolet-visible(UV-VIS)spectrum.