简介:摘要;本设计采用电感耦合等离子发射光谱法(ICP—OES)对岩石样品中的Cu,Pb,Zn,Mn,Ni进行了测定,样品用四酸()熔矿,不经分离杂质,即可直接测定。该方法选择Cu,Pb,Zn,Mn,Ni的测定分析波长分别为324.7nm,220.3nm,202.5nm,257.6nm,221.6nm分析了用HCl提取与用王水提取,样品首先经磨样机碎至200目,用去离子水湿润后,用四酸熔矿,再将坩埚放置恒温电热板上加热,最后分别用王水或盐酸提取再定容,对其中的Cu,Pb,Zn,Mn,Ni做探究实验。
简介:TheelectronicpropertiesandtopologicalphasesofThXY(X=Pb,Au,Pt,PdandY=Sb,Bi,Sn)compoundsinthepresenceofspin–orbitcoupling,usingdensityfunctionaltheoryareinvestigated.TheThPtSncompoundisstableintheferromagneticphaseandtheotherThXYcompoundsarestableinnonmagneticphases.Bandstructuresofthesecompoundsintopologicalphases(insulatorormetal)andnormalphaseswithingeneralizedgradientapproximation(GGA)andEngel–Voskogeneralizedgradientapproximation(GGAEV)arecompared.TheThPtSn,ThPtBi,ThPtSb,ThPdBi,andThAuBicompoundshavetopologicalphasesandtheotherThXYcompoundshavenormalphases.Bandinversionstrengthsandtopologicalphasesofthesecompoundsatdifferentpressurearestudied.Itisseenthatthebandinversionstrengthsofthesecompoundsaresensitivetopressureandforeachcompoundasecond-orderpolynomialfittedonthebandinversionstrengths–pressurecurves.
简介:采用原子吸收分光光度法研究龟裂链霉菌GQ-17(StreptomycesrimosusGQ-17)菌体对重金属Pb-(2+)的吸附能力,并优化最佳吸附条件,初步探讨了Pb-(2+)对抑菌活性的影响。结果表明,菌株GQ-17在48℃、pH为10.0、初始Pb-(2+)质量浓度为7000mg·L-1的条件下处理60min对Pb-(2+)吸附量最大。此外,在GQ-17发酵初期加入Pb-(2+)质量浓度为700mg·L-(-1)时发酵液对黄瓜枯萎病菌的抑制活性有所增大。GQ-17的菌体具有重金属离子吸附潜力,并且少量Pb-(2+)的存在能刺激抑菌活性物质的产生。这为研发新型生物吸附剂和提高活性物质产量提供了新资源。
简介:为了解重金属污染对海洋鱼类热休克蛋白(HSPs)基因表达的影响,将褐菖鲉(Sebastiscusmarmoratus)分别暴露于1.6、8、40、200、500μg·L^-1Cd、Pb溶液中,用环介导等温扩增技术(loop-mediatedisothermalamplification,LAMP)定量检测褐菖鲉肝脏HSP60、HSP70、HSP90、HSC70mRNA表达量。结果表明:Pb仅在40μg·L^-1时显著抑制HSP60、HSP90、HSC70mRNA表达量,8μg·L^-1时即可显著抑制HSP70mRNA表达量,并在40μg·L^-1时达到最小值;Cd对HSP60、HSP90、HSC70的诱导不明显,但能显著诱导HSP70,并在500μg·L^-1时达到最大值。相比之下,褐菖鲉肝HSP70基因对重金属Cd、Pb污染较为敏感,有潜力成为监测海洋重金属污染的预警分子。
简介:WeperformedasystematictraceandrareearthelementanalysisforthebeddedFe-MncarbonaterocksrelatedtothestratiformAg-Pb-ZnmineralizationintheLengshuikengoredistrict,JiangxiProvince,SouthChina.ThreetypesofFe-Mncarbonatesaredistinguished,namely,themassive,breccia,andveintypes.Bothcarbonateandsilicatefractionsinthesamplesareanalyzedfortheirtraceandrareearthelementconcentrationsusingastepacid-leachingtechnique.OurresultsshowthatthecarbonatefractionsinthemassivetypesampleshavethelowestREEconcentrationsbutpronouncedpositiveEuandYanomalieswithEu/Eu*valuefrom1.3to6.2andY/Hovaluefrom40.1to59.5,andsimilarcharacteristicsarealsoshownforthesilicatefractionsinthemassivetypesamples(Eu/Eu*=1.0–6.7,Y/Ho=20.7–55.1).TheseREEcharacteristicsaresimilartothoseofSedextypemassivesulfidedepositsworldwide,andwesuggestthatthemassivetypeFe-Mncarbonaterockswerelikelyformedfromanexhalativevolcanic-hydrothermalfluidfeedingthedepressionbasinofavolcaniclake.Thehighconcentrationsofredox-sensitiveelementsandratiossuchasU/Th,V/CrandV/(V+Ni)indicateadysoxicenvironmentfortheFe-Mncarbonatedeposition.Incontrast,thebrecciatypeandveintypeFe-Mncarbonatesamplesshowdifferenttraceandrareearthelementfeaturesfromthoseofmassivetypesamples,andtheyaremoresimilartothevolcanicrocksandmagmatic-hydrothermalfluidsintheLengshuikengoredistrictandmayreflectstrongoverprintingfromvolcanicandsub-volcanicmagmatismrelatedtotheporphyrytypemineralizationinthedistrict.