简介:双相不锈钢1Cr18Ni11Si4AlTi由前苏联研制,目前在我国某些特殊行业中有重要的作用。根据我国现有标准GJB2294—95和GB/T1220—92组织生产,发现按标准中现行成分设计、热处理制度生产的产品与标准要求的力学性能(屈服强度σ0.2)需达到的规定值存在较大差异,很难达到所需要的屈服强度。通过完善相关成分和工艺参数,获得了满意的金相组织和优良的综合力学性能。通过试验探讨了生产实际与标准中的部分规定存在的差距。
简介:Themicrostructuralevolutionsofadvanced9-12%Crferrite/martensiteheat-resistantsteelsusedforpowergenerationplantsarereviewedinthisarticle.Despiteofthesmalldifferencesinchemicalcompositions,thesteelssharethesamemicrostructureoftheas-temperedmartensite.Itisthethermalstabilityoftheinitialmicrostructurethatmattersthecreepbehavioroftheseheat-resistantsteels.Themicrostructuralevolutionsinvolvedin9-12%Crferriteheat-resistantsteelsareelabo-rated,including(1)martensiticlathwidening,(2)disappearanceofprioraustenitegrainboundary,(3)emergenceofsubgrains,(4)coarseningofprecipitates,and(5)formationofnewprecipitates,suchasLaves-phaseandZ-phase.Theformerthreemicrostructuralevolutionscouldberetardedbyproperlydisposingthelattertwo.Namelyimprovingthestabilityofprecipitatesandoptimizingtheirsizedistributioncaneffectivelyexertthebeneficialinfluenceofprecipitatesonmicrostructures.Inthissense,themicrostructuralstabilityofthetemperedmartensiteisinfactthestabilityofprecipitatesduringthecreep.Manyattemptshavebeencarriedouttoimprovethemicrostructuralstabilityof9-12%Crsteelsandseveralpromisingheat-resistantsteelshavebeendeveloped.
简介:DropletsofCo-37.6wtpctMoandNi-47.7wtpctMoeutecticalloyswererapidlysolidifiedduringcontainerlessprocessingina3mdroptube.Akindofanomalouseutecticappearsinthesetwoeutecticalloyswhenundercoolingisbeyond56and61K,respectively.Thetwoeutecticphasesinanomalouseutecticwereobservedtogrowindendritemanner.Theformationofanomalouseutecticisascribedtothecooperativedendritegrowthofthetwoindependentlynucleatedeutecticphases.Currentdendriteandeutecticgrowththeoriesareappliedtodescribetheobservedprocesses.
简介:Anovelfluorescentprobe9-(4-(1,2-diamine)benzene-N1-phenyl)acridine(DABPA)wassynthesizedforthedetectionofnitricoxide(NO)andcharacterizedbyIR,1H-NMRandEI-MSspectroscopy.Basedonaphotoelectrontransfermechanism,thefluorescenceintensitiesofDABPAwereinvestigatedwiththedifferentconcentrationsofNO.Undertheoptimalexperimentalconditions,thefluorescenceintensityofDABPAhadagoodlinearrelationship(R2=0.9977)withNOconcentrationintherangefrom1×10-7to1.5×10-6mol/Lwithadetectionlimitof1×10-8mol/L.ThecytotoxicityinducedbyDABPAwasevaluatedbytheMTT(3-(4,5-dimethylthiazol-2-yl)-2,5diphenyltetrazoliumbromide)assayforbiologicalapplication.Furthermore,theprobeDABPAhadalsobeensuccessfullyappliedtoreal-timeimageNOproducedinPC12cellsinthepresenceofL-arginine.
简介:利用XRD、SEM等分析手段,对含微量Zr、Ti的Cr35Ni45Nb合金的力学性能和微观组织相互关系进行了研究。结果表明,该合金组织为奥氏体基体和枝晶间骨架状碳化物,碳化物类型为富铬的M23C6和含铌等强碳化物元素组成的MC;微量Zr、Ti可细化二次析出的Cr35Ni45Nb合金中的碳化物,使其呈粒状较均匀地分布在晶内,从而提高合金的力学性能。
简介:PrecipitationstudywascarriedoutinNi-35at.pctCralloybymeasuringelectricalresistivityatdifferentageingtemperaturesandlongageingtimes.Duringageing,itwasobservedthatelectricalresistivityinitiallyrosewithageingtimeandthenfellafterverylongageingataconstanttemperature.TheinitialincreaseinresistivityduringageingmaybeattributedtotheformationofGPzones/Cr-richprecipitatesatearlystagesbynucleationprocessanddecreaseinresistivity,andafterattainingamaximum,isduetothegrowthofprecipitateparticlesandsubsequentlybycoarseningoftheseprecipitates.TheresultsofelectricalresistivitymeasurementsduringageingwereconfirmedbyX-raydiffractionanalysisindicatingtheformationofaCr-richphaseandaCr3Ni2phaseintheNimatrix.
简介:Combustionreactionwelding,onepromisingmethodtoweldceramicsandmetals,wasusedtoweldTiB2andMo.TheresultsshowedthatthereactedproductsthroughcombustionreactionwereTiB2andMoBwhentheMocontentsinreactantswere20wtpctand40wtpctwhiletherewasMobesidesMoBandTiB2whentherewere60wtpctand80wtpctMoinreactants.Diffusionofelementsoccurredattheinterfacesofthetwosubstrates.Theinterfacesbetweenthereactedandthetwosubstrateswereindistinctafterbeingwelded.Theweldingtemperaturestronglyaffectedpropertiesofthesamples.Thevalueofbendingstrengthofthesamplewith80wtpctMoinreactantweldedat1500℃wasthehighest,368.52MPa.Thehighestvalueofshearstrengthamongallthesampleswasthatoftheonewith40wtpctMoinreactantweldedat1500℃,50.97MPa.
简介:1.IntroductionLightrareearthadditioncanremarkablyenhancetheservicelifeofFe-Cr-Alalloyforelectricalheatingelement,butitscontentinthealloymustbecontrolledbelowthelevelof0.1wt-%.Whenthecontentexceedsthat,theperformance
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