简介:利用角分辨紫外光电子谱对乙烯和乙炔气体在Ru(1010)表面的吸附及与K的共吸附的研究结果表明:当衬底温度超过200K,乙烯即发生脱氢反应,σCH和σCC能级均向高结合能方向移动。在室温下,σCH和σCC能级位置与乙炔在Ru(1010)表面的吸附时的分子能级完全一致。乙烯发生脱氢反应后的主要产物为乙炔。衬底温度从120K到室温,Ru(1010)表面上乙炔的σCH和σCC能级均未发现变化。室温下乙炔仍然可以在Ru(1010)表面以分子状态稳定吸附。在有K的Ru(1010)表面上,室温时σCC谱峰几乎。碱金属K的存在促进了乙炔的分解。
简介:Carbonnanotube(CNT)-supportedRunanoparticleswithmeansizesrangingfrom2.3to9.2nmwerepreparedbydifferentpost-treatmentsandstudiedforFischer-Tropsch(FT)synthesis.TheeffectsofRuparticlesizeoncatalyticbehaviorswereinvestigatedatbothshorterandlongercontacttimes.Atshortercontacttime,wherethesecondaryreactionswereinsignificant,theturnoverfrequency(TOF)forCOconversionwasdependentonthemeansizeofRuparticles;TOFincreasedwiththemeansizeofRuparticlesfrom2.3to6.3nmandthendecreasedslightly.Atthesametime,theselectivitiestoC5+hydrocarbonsincreasedgraduallywiththemeansizeofRuparticlesupto6.3nmandthenkeptalmostunchangedwithafurtherincreaseinRuparticlesize.Atlongercontacttime,C10-C20selectivityincreasedsignificantlyattheexpenseofC21+selectivity,suggestingtheoccurrenceoftheselectivehydrocrackingofC21+toC10-C20hydrocarbons.
简介:墨玉祥云,雅致外观HPMINI1010TU的机身外壳采用流行的膜内漾印技术,黑色如墨玉般的顶盖上印着不规则的祥云暗纹,雅致的外观让它脱俗于变幻不定的流行风潮,发散出中国风情的艺术品味。外观尺寸方面MINI1010与一般上网笔记本大小相
简介:Polyamide-1010sampleswereirradiatedinvacuumatroomtemperaturebyCobalt-60γ-rays.Thefreeradicalsformedinirradiationwerestudiedbymeansofelectronspinresonance(ESR)techniques.TheESRspectraconsistedofaquartetandasuperimposedsingletwhichwereattributedtoradical-CO-NH-CH-CH2and-CH2-C=O,respectively.TheeffectsoftemperatureandcrystaUinityontheradicalswerediscussedandthemechanismfortheproductionanddecayoftheradicalswasalsoproposed.
简介:在现在的工作,一系列Ta/Ru/Co-23?at%Pt有改变的Ruunderlayer厚度的薄电影被磁控管劈啪作响制作。所有这些电影证明c轴比较喜欢对电影表面垂直的取向。c/a比率和有Ruunderlayer厚度的增加的埃及土人层的格子扩大的落下被X光检查衍射(XRD)揭示。Ta/Ru/Co-Pt薄电影的coercivity与Ruunderlayer厚度增加急速地增加,由于有效磁电机水晶的anisotropy常数的改进和磁性的nano谷物的交换去耦。有效磁电机水晶的anisotropy常数的改进被错配Ru层和埃及土人表面归功于到埃及土人层的格子变丑。而且,磁性的nano谷物的交换去耦被归因于磁性的nano谷物的进一步的隔离。
简介:ThestructureofaggregationstateandisothermalcrystallizationbehaviorofNylon-1010havebeenstudiedbyWAXD,DSE,Variance-RangeFunctionanddensitymeasurement.TheresultsshowthatcrystallizationofNylon-1010hasthemostsuitableannealingtemperature,thecrystalsoftheNxlon-1010aretwo-dimensionheterogeneousnucleation.Bothlowtreatmenttemperatureandhighcrystallizationte,temperaturearedisadvantageousforNylon-1010crystalgrowth.
简介:大音阶的第五音胶化旋转涂层在Pt/Ti/SiO2/Sisubstrate上准备的Pb(Zr0.4Ti0.6)O-3电影作为最高的电极与磅或Ru被用于铁电体电容器。为thePt/PZT/Pt和Ru/PZT/Pt铁电体电容器,尽管与一样的铁电体他,不同最高的电极材料招致PZT电容器的不同性质例如疲劳,漏,残余、浸透的极化,除了PZTfilm的类似的水晶取向。在(10)10交换周期以后,Ru/PZT/Pt和Pt/PZT/Ptcapacitors的残余的极化分别地减少到70%和84%。在(8)10交换周期以后,后者的漏水流密度在积极偏爱显然增加,与前者相比。为最高的电极的Differentmaterials在PZT/top电极接口带不同条件。在PZT/electrode接口和在到充电注射的PZT/electrode接口的电极材料的氧化物的影响的氧空缺集中的Theinfluence能作为最高的电极与磅或Ru解释PZT电容器的性质的差别。
简介:TheeffectofacidcomponentincludingvariousconventionalacidsandtungsticcompoundsonglucosehydrogenationoveraseriesofbinarycatalystsystemcontainingRu/Ccatalystwasinvestigated.TheresultsshowedthatHCl,H2SO4,H3BO3,H3PO4,andHNO3hadnegligibleeffect,whileallthetungsticcompoundsimposedinhibitingeffectsonthehydrogenationofglucoseoverRu/Ccatalyst,andthesuppressingeffectfollowedtheorderofH2WO4>HPW>WO3>AMT>HSiW.Thisorderisthesameastheorderofethyleneglycol(EG)yieldsintheone-potconversionofglucosetoEG,suggestingtheimportantroleofcompetitionbetweenglucosehydrogenationandretro-aldolcondensationincontrollingtheselectivityofEG.
简介:Highspinstatesintheneutron-rich^108Runucleushavebeenstudiedthroughmeasuringpromptγ-raycoincidencesfollowingthespontaneousfissionof^252CfwiththeGammaspheredetectorarray.Theyrastbandhasbeenconfirmed.Theone-phononγ-vibrationalbandandthetwo-quasiparticlebandbasedonthe5^-levelhavebeenextendedupto13^+and15^-,respectively.Inaddition,twolevelsat1644.8keVand1826.5keVexcitationenergiesarenewlyidentifiedandproposedtobethemembersofatwo-phononγ-vibrationalband.Itisshownthatthe^108Runucleushastriaxialdeformationwithparametersβ2~0.29andγ=-22°fromthetotalRouthiansurfacecalculations.Theobservedbandcrossingintheyrastbandisduetothealignmentofapairofh11/2neutronsaccordingtothecrankedshellmodelcalculations.Thepossibleconfigurationforthetwo-quasiparticlebandhasbeendiscussed.