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84 个结果
  • 简介:Oxidationprocessoflanthanumhexaboride(LaB6)ceramicpowderwasinvestigated.TheLaB6powdersampleswereheatedcontinuallyfromroomtemperatureto1473Kataheatingrateof10K/minbydifferentialscanningcalorimetry.Theoxidationtestswereconductedatdifferentexposuretemperatures.ThephasesandmorphologiesofthesamplesbeforeandafterexposurewereanalyzedbyXRDandSEM.Itwaspointedoutthatbefore1273K,LaB6hashighoxidationresistantability,whichwasduetothattheoxidelayerhinderstheoxygendiffusionfromoutertothesurfaceofLaB6grains.Theoxidelayerwascomposedofthetransitionphases,whichwerecomposedofLa2O3andB2O3formedfromtheinitialoxidation;whentheoxidationtemperatureexceeded1273K,protectivelayerwasdestroyedduetothevaporizationofliquidB2O3.BasedontheresultsofX-raydiffractionanalysis,oxidationprocessofLaB6ceramicpowdercanbedescribedasfollows:Before1273K,lanthanumborate,La(BO2)3wasformedonthesurfaceofsamples,thenlanthanumoxide(La2O3)andboronoxide(B2O3)werepresentonthesurfaceofsamplesoxidizedwhenthetemperaturereachedto1473K.

  • 标签: 六溴化镧 氧化 陶瓷 稀土 XRD 高温结构材料
  • 简介:Compressedthinlayersofceramicfiberinsulationareusedashightemperatureinsulatinglayersaswellasmechanicalsupportforcatalystcoatedceramicmonolithsinautomotiveemissioncontroldevices.Minimizationofenergylosses,choiceofmaterialandthicknessofcompressedinsulatinglayerarebasedonknowledgeoftheirthermalphysicalproperties.Currently,consistentmeasurementsofmaterialsinacompressedstate,astheywouldbeinemissioncontrolapplications,areabsentduetotheabsenceofsuitablemethodsforsuchtests.Atestmethodwasdevelopedformeasurementofthethermalconductivityofcompressedthinfiberlayers.Thispapersummarizestheresultsofthermalconductivityanddiffusivitymeasurementsof27compressedfiberalumina-silica-vermiculitematerialsintherangeof200-950℃.Thermalphysicalpropertiesasafunctionoftemperature,density/mechanicalpressure,thicknessandcompositionofinsulatinglayersarepresented.Thewholesetofexperimentaldataisgeneralizedon3Dsurfaceplotsanddescribedbypolynomialfunctions.Thepossibleheattransfermechanismsgoverningapparentthermalconductivityofpressedinsulationlayersarediscussed.

  • 标签: 压缩状态 陶瓷纤维 绝缘层 排放控制装置 表观导热系数 热物理性能
  • 简介:TransparentYAG(yttriumaluminumgarnet)ceramicswerefabricatedbysolid-statereactionmethod.Effectofadditive(tetraethylorthosilicate,TEOS)onmicrostructureofYAGceramicswasinvestigated.IftheadditionofTEOSismorethan3%(massfraction),largeamountofliquidphasecanbeyieldedatgrainboundaries,resultingintheformationofsecondphaseparticlesatgrainboundaries.Iftheadditionislessthan0.05%(massfraction),poresareentrappedinthegrains.Thesuitableamountis0.5%(massfraction).AfullytransparentYAGceramicwasfabricatedbyvacuumsinteringat1700℃for5h.OpticaltransmittanceoftheYAGceramicis63%inthevisiblelightwavelengthsand70%intheinfraredwavelengths.

  • 标签: 无机材料 YAG 透明陶瓷 稀土 光学陶瓷
  • 简介:Mechanicalandelectricaldamagesareintroducedtostudythefracturemechanicsofpiezoelectricceramicsinthispaper.Twokindsofpiezoelectricfracturecriteriaareestablishedusingthemethodofleastsquarescombinedwithadamageanalysisofthewell-knownpiezoelectricfractureexperimentsofParkandSun's.Oneisbasedonalinearcombinationofthemechanicalandelectricaldamagesandtheotherontheirnonlinearcombination.WhenthecombineddamageDisuptoitscriticalvalueDc,piezoelectricfractureoccurs.Itisfoundfromthequalitativecomparisonofthenumericalresultswiththeexperimentaldatathatthenonlinearlycombineddamagefracturecriterioncangiveabetterpredictionofpiezoelectricfracture.Anditisconcludedfromthenonlinearlycombineddamagefracturecriterionthatanegativeelectricfieldimpedesfracturewhereastheeffectofapositiveelectricfieldonfracturedependsonitsmagnitude.

  • 标签: 电力耦合 混合损伤 断裂标准 压电陶瓷
  • 简介:ThefracturetoughnessofMgOpartiallystabilizedzirconia(MgO-PSZ)hasbeenmea-suredbythehardnessindentationmethod.TheinfluencesofheattreatmentonthefracturetoughnessK1cofMgO-PSZwerestudied,ItwasfoundthatthefracturetoughnessofMgO-PSZcanbegreatlychangedbydifferentheattreatmentprofile.Thefracturetoughnesswasimprovedbytheheattreatmentat1100℃afteragingat1400℃,TherewasthegreatestK1cvalue(11.30MPa.m^1/2)ofthesamplesagedat1400℃for2hfollowedbyasubse-quentannealat1100℃for10h.ThechangesinthemicrostructureofMgO-PSZceramicsagedwithdifferentthermaltreatmentwerestudieddbyuseoftransmissionelectronmicroscopy.

  • 标签: 氧化镁 MGO PSZ 微观结构 韧化处理 部分稳定氧化锆
  • 简介:Ceramics,Pottery.Stoneware.Earthenware这是一组有关"陶瓷"的词。几乎所有英汉词典和英汉美术词典都把这四个词解释为:ceramics(总称)陶器;pottery(集合词)陶器类、陶器(总称):stoneware缸器粗陶(器):earthenware(集合词)陶器。1.按照上述解释,除stoneware外,其余三个词皆为陶器,这三个词之间有什么联系?有什么不同呢?它们所指的是否是同种东西?

  • 标签: 粗陶器 陶瓷技术 英汉双解辞典 解释 不同含义 瓷器
  • 简介:Basedonshearlagmodelofinterfacebetweenfiberandmatrix,anewformulathatre-latesthecrackopeningdisplacementandbridgingforceinfibrousmonolithicceramicswasconstructedundertheframeworkofsmallscalebridging.Thisformulawasappliedtopredictthefractureresis-tanceorR-curveresponseofathree-pointbendingspecimenmadeoffibrousmonolithicceramics.Aparametricinvestigationontheinfluencesoffibervolumefraction,fiberradius,characteristicsofconstituents,BN’sfracturetoughnessandspecimen’sgeometryonthebridgingforcesandfracturere-sistanceinSi3N4/BNcompositewascarriedout.TheupperandlowerlimitsoftheR-curveofSi3N4/BNinsmallscalebridgingwerederived,Thisresearchrevealedtheroleplayedbytheaboveparame-tersinthefracturetoughnessoffibrousmonolithicceramics.

  • 标签: FIBROUS MONOLITHIC CERAMICS fiber BRIDGING R-CURVE
  • 简介:Recentprogressonrare-earthdopedpolycrystallineYAGtransparentceramicshasmadethemanalternativenovelsolid-statelasergainmaterial.Inthispaper,wepresentresultsofourresearchonpolycrystallineRE:YAGtransparentceramics.HighopticalqualityYAGceramicsdopedwithvariousrare-earth(RE)ionssuchasNd3+,Yb3+,Er3+,Tm3+,andHo3+havebeensuccessfullyfabricatedusingthesolid-statereactivesinteringmethod.Highlyefficientlaseroscillationsofthefabricatedceramicsaredemonstrated.

  • 标签: RE:YAG SOLID STATE LASERS TRANSPARENT CERAMICS
  • 简介:以便讨论修改La的铅锆酸盐titanate锡酸盐antiferroelectric陶艺PbLaZr的非线性的机电的性质,Sn,TiO3PLZST,近似线性化的电致伸缩的方程古典线性压电的方程从秒顺序被导出的一模一样的形式概括压电的方程称为。解决非线性的antiferroelectric阶段转变陶艺变换器的电声的transduction问题的一条分析途径被介绍。PLZST的非线性的性质能基于为分析变换器的电声的transduction问题的近似线性化的电致伸缩的方程与维持的偏爱是线性地相等的。创新antiferroelectric陶艺有回声频率1.1kHz的低频率班IVflextensional变换器基于途径被开发它作为活跃元素利用PLZST。湖认证显示为变换器的PLZST的使用一会儿在它的PZT-4对应物上在在SL的TVR和9dB增加产出3dB增加,并且途径是有效的。

  • 标签: 反铁电陶瓷 相变陶瓷 非线性光学性质 低频 投影机 PLZST
  • 简介:Yttriumaluminumgarnet(YAG)transparentceramicswerefabricatedbysinteringatoxygenatmosphere.Tetraethylorthosilicate(TEOS)wasaddedasthesinteringadditivetocontrolthegraingrowthanddensification.Poreswereeliminatedclearlyattemperaturelowerthan1700oC,whilegrainsizewasaround3μm.Thein-linetransmittancewas80%at1064nmwhensamplesweresinteredat1710oC.TheeffectofTEOSwasstudiedinoxygenatmospheresinteringforNd:YAGtransparentceramics.Athighertemperaturelike1710oC,thegraingrowthmechanismwassolutedrag,whileat1630and1550oCthegraingrowthwascontrolledbyliquidphasesinteringmechanism.And0.5wt.%TEOSwasthebestaddingcontentforNd:YAGsinteredinoxygenatmosphere.

  • 标签: Nd YAG陶瓷 烧结助剂 氧气氛 晶粒生长 TEOS
  • 简介:Itisexpectedthatinthenewcentury,tocopewithdevelopmentsofnewhightemperaturetechnologies,anewgenerationofhighperformancerefractoryceramicswillemergeandflourishwhichshouldincludethefollowing(1)oxideandnonoxidecompositescharacterizedbyauniquecombinationofhighhotstrength,highthermalshockresistanceandhighcorrosionresistance;(2)freeCaObearingbasicrefractoriescapableofpurifyingmoltenmetalforimprovingcleanlinessandofabsorbingcontaminantsfromwastegasesforreducingenvironmentalpollution;(3)freeflowingzerocementcastableswithimprovedthermomechanicalproperties,thermalshockresistanceandcorrosionresistanceandgradientcastableswithvaryingmatrixcompositionandvaryingtexture.

  • 标签: 耐火陶瓷材料 氧化复合材料 氧化钙 非氧化复合材料
  • 简介:堇青石蜂房陶艺与1.5MHNO_3被对待,在93degC与1.5MNaOH列在后面有碱处理的酸处理的联合显著地减少了热扩大(CTE)的系数反弹由热处理引起了,在完全与酸对待的样品观察的现象。诱导地联合的血浆(ICP)分析结果表明碱处理优先地溶解了在acid-treatedsamples离开的“免费”的SiO_2,它为反弹的CTE被认为是一个关键因素负责。

  • 标签: 堇青石陶瓷学 碱处理 热膨胀系数 化学处理 蜂窝状陶瓷
  • 简介:ZhengzhouUniversityniversitiesinChinaandisoneofthenationalkeyuisjointlysupportedbytheMinistryofEducationandHenanProvincialGovernment.ItislocatedinZhengzhoucity,capitalofHenanprovinceincentralChinawhichisthecradleofChineseculture.Theuniversitycampuscoversanareaof4.3millionm2.Thereare40thousandundergraduateand3600post-graduatestudents.Itsceramicsdepartmentenrollsabout350students.

  • 标签: 制陶业研究所 郑州大学 河南 科研工作
  • 简介:Macroporoussiliconnitride(Si3N4)ceramicswithhighstrength,uniformstructureandrelativelyhighporositywereobtainedbygelcastingandcarbonthermalreactioninatwo-stepsinteringtechnique.Microstructureandcompositionwereinvestigatedbyscanningelectronmicroscopy(SEM),transmissionelectronmicroscopy(TEM),X-raydiffraction(XRD).Openporosity,poresizedistributionandbasicmechanicalperformanceweremeasuredbyArchimedesmethod,mercuryintrusionporosimetryandthree-pointbendingmethods,respectively.SEMandTEMresultsrevealedthatporeswereformedbyelongatedβ-Si3N4.SADPmeasurementprovedtheformationofSiCparticles.TheSiCgranuleswerebeneficialfortheformationofhighratioelongatedβ-Si3N4,andatproperamount,theyalsoactedasreinforcementphase.Thermodynamicanalysisindicatedthatthemechanismsofthereactionsweremainlyassociatedwithliquid-solidreactionandgas-liquidreaction.

  • 标签: 氮化硅 碳热作用 制陶术 X射线衍射 大孔材料
  • 简介:Magnificent&GorgeousTheShanghaiCommunication&FinanceMansiondesignedbyWangShiwei,GeneralDesigner,wontheSpecialAwardinthe“2004DongpengInteriorDesigningCompetition”organizedbytheChinaConstruction&DecorationAssociation.

  • 标签: 陶瓷行业 环境保护 发展战略 清洁生产
  • 简介:DopedSrTiO3capacitor-varistormultifunctionalceramicswerefabricatedbyasinglesinteringprocess.ACcompleximpedanceanalysiswasperformedtoinvestigateelectricalfeaturesofgrainsandgrainboundariesforbothas-reducedceramicandreoxidizedceramics.Theresultsshowedthattheas-reducedceramicexhibitedinductiveresponseathighfrequenciesabove2MHz,whichisattributedtothecontributionofelectronbehaviorinsemiconductinggrains.Thehighfrequencyinductiveresponsedisappearedinimpedanceplotsofreoxidizedceramics.

  • 标签: 钛酸锶 多功能陶瓷 阻抗分析
  • 简介:以便在oxyfluoride眼镜和玻璃陶艺的形成上调查不同重金属离子的影响,有不同PbF2/CdF2比率的样品被融化熄灭和热处理方法准备了。玻璃网络结构上的Pb2+和Cd2+的不同效果被FTIR和拉曼系列调查。在玻璃网络结构的形成期间,Pb2+喜欢打破Si–O–Si契约并且随后为起诉赔偿结合到F−,并且Cd2+喜欢打破Si–O–Al契约并且被O2−包围。Pb2+和F−一起聚在一起并且形成氟化物nanocrystals,当Cd2+在热处理以后留在氧化物矩阵时。合适的CdF2的介绍是重要的在透明玻璃陶艺的制造调整并且控制玻璃网络结构和结晶化过程。

  • 标签: 氟氧化物玻璃 玻璃陶瓷 重金属离子 网络结构 拉曼光谱 电荷补偿