简介:Oxidationprocessoflanthanumhexaboride(LaB6)ceramicpowderwasinvestigated.TheLaB6powdersampleswereheatedcontinuallyfromroomtemperatureto1473Kataheatingrateof10K/minbydifferentialscanningcalorimetry.Theoxidationtestswereconductedatdifferentexposuretemperatures.ThephasesandmorphologiesofthesamplesbeforeandafterexposurewereanalyzedbyXRDandSEM.Itwaspointedoutthatbefore1273K,LaB6hashighoxidationresistantability,whichwasduetothattheoxidelayerhinderstheoxygendiffusionfromoutertothesurfaceofLaB6grains.Theoxidelayerwascomposedofthetransitionphases,whichwerecomposedofLa2O3andB2O3formedfromtheinitialoxidation;whentheoxidationtemperatureexceeded1273K,protectivelayerwasdestroyedduetothevaporizationofliquidB2O3.BasedontheresultsofX-raydiffractionanalysis,oxidationprocessofLaB6ceramicpowdercanbedescribedasfollows:Before1273K,lanthanumborate,La(BO2)3wasformedonthesurfaceofsamples,thenlanthanumoxide(La2O3)andboronoxide(B2O3)werepresentonthesurfaceofsamplesoxidizedwhenthetemperaturereachedto1473K.
简介:Compressedthinlayersofceramicfiberinsulationareusedashightemperatureinsulatinglayersaswellasmechanicalsupportforcatalystcoatedceramicmonolithsinautomotiveemissioncontroldevices.Minimizationofenergylosses,choiceofmaterialandthicknessofcompressedinsulatinglayerarebasedonknowledgeoftheirthermalphysicalproperties.Currently,consistentmeasurementsofmaterialsinacompressedstate,astheywouldbeinemissioncontrolapplications,areabsentduetotheabsenceofsuitablemethodsforsuchtests.Atestmethodwasdevelopedformeasurementofthethermalconductivityofcompressedthinfiberlayers.Thispapersummarizestheresultsofthermalconductivityanddiffusivitymeasurementsof27compressedfiberalumina-silica-vermiculitematerialsintherangeof200-950℃.Thermalphysicalpropertiesasafunctionoftemperature,density/mechanicalpressure,thicknessandcompositionofinsulatinglayersarepresented.Thewholesetofexperimentaldataisgeneralizedon3Dsurfaceplotsanddescribedbypolynomialfunctions.Thepossibleheattransfermechanismsgoverningapparentthermalconductivityofpressedinsulationlayersarediscussed.
简介:TransparentYAG(yttriumaluminumgarnet)ceramicswerefabricatedbysolid-statereactionmethod.Effectofadditive(tetraethylorthosilicate,TEOS)onmicrostructureofYAGceramicswasinvestigated.IftheadditionofTEOSismorethan3%(massfraction),largeamountofliquidphasecanbeyieldedatgrainboundaries,resultingintheformationofsecondphaseparticlesatgrainboundaries.Iftheadditionislessthan0.05%(massfraction),poresareentrappedinthegrains.Thesuitableamountis0.5%(massfraction).AfullytransparentYAGceramicwasfabricatedbyvacuumsinteringat1700℃for5h.OpticaltransmittanceoftheYAGceramicis63%inthevisiblelightwavelengthsand70%intheinfraredwavelengths.
简介:Mechanicalandelectricaldamagesareintroducedtostudythefracturemechanicsofpiezoelectricceramicsinthispaper.Twokindsofpiezoelectricfracturecriteriaareestablishedusingthemethodofleastsquarescombinedwithadamageanalysisofthewell-knownpiezoelectricfractureexperimentsofParkandSun's.Oneisbasedonalinearcombinationofthemechanicalandelectricaldamagesandtheotherontheirnonlinearcombination.WhenthecombineddamageDisuptoitscriticalvalueDc,piezoelectricfractureoccurs.Itisfoundfromthequalitativecomparisonofthenumericalresultswiththeexperimentaldatathatthenonlinearlycombineddamagefracturecriterioncangiveabetterpredictionofpiezoelectricfracture.Anditisconcludedfromthenonlinearlycombineddamagefracturecriterionthatanegativeelectricfieldimpedesfracturewhereastheeffectofapositiveelectricfieldonfracturedependsonitsmagnitude.
简介:ThefracturetoughnessofMgOpartiallystabilizedzirconia(MgO-PSZ)hasbeenmea-suredbythehardnessindentationmethod.TheinfluencesofheattreatmentonthefracturetoughnessK1cofMgO-PSZwerestudied,ItwasfoundthatthefracturetoughnessofMgO-PSZcanbegreatlychangedbydifferentheattreatmentprofile.Thefracturetoughnesswasimprovedbytheheattreatmentat1100℃afteragingat1400℃,TherewasthegreatestK1cvalue(11.30MPa.m^1/2)ofthesamplesagedat1400℃for2hfollowedbyasubse-quentannealat1100℃for10h.ThechangesinthemicrostructureofMgO-PSZceramicsagedwithdifferentthermaltreatmentwerestudieddbyuseoftransmissionelectronmicroscopy.
简介:Basedonshearlagmodelofinterfacebetweenfiberandmatrix,anewformulathatre-latesthecrackopeningdisplacementandbridgingforceinfibrousmonolithicceramicswasconstructedundertheframeworkofsmallscalebridging.Thisformulawasappliedtopredictthefractureresis-tanceorR-curveresponseofathree-pointbendingspecimenmadeoffibrousmonolithicceramics.Aparametricinvestigationontheinfluencesoffibervolumefraction,fiberradius,characteristicsofconstituents,BN’sfracturetoughnessandspecimen’sgeometryonthebridgingforcesandfracturere-sistanceinSi3N4/BNcompositewascarriedout.TheupperandlowerlimitsoftheR-curveofSi3N4/BNinsmallscalebridgingwerederived,Thisresearchrevealedtheroleplayedbytheaboveparame-tersinthefracturetoughnessoffibrousmonolithicceramics.
简介:Recentprogressonrare-earthdopedpolycrystallineYAGtransparentceramicshasmadethemanalternativenovelsolid-statelasergainmaterial.Inthispaper,wepresentresultsofourresearchonpolycrystallineRE:YAGtransparentceramics.HighopticalqualityYAGceramicsdopedwithvariousrare-earth(RE)ionssuchasNd3+,Yb3+,Er3+,Tm3+,andHo3+havebeensuccessfullyfabricatedusingthesolid-statereactivesinteringmethod.Highlyefficientlaseroscillationsofthefabricatedceramicsaredemonstrated.
简介:以便讨论修改La的铅锆酸盐titanate锡酸盐antiferroelectric陶艺PbLaZr的非线性的机电的性质,Sn,TiO3PLZST,近似线性化的电致伸缩的方程古典线性压电的方程从秒顺序被导出的一模一样的形式概括压电的方程称为。解决非线性的antiferroelectric阶段转变陶艺变换器的电声的transduction问题的一条分析途径被介绍。PLZST的非线性的性质能基于为分析变换器的电声的transduction问题的近似线性化的电致伸缩的方程与维持的偏爱是线性地相等的。创新antiferroelectric陶艺有回声频率1.1kHz的低频率班IVflextensional变换器基于途径被开发它作为活跃元素利用PLZST。湖认证显示为变换器的PLZST的使用一会儿在它的PZT-4对应物上在在SL的TVR和9dB增加产出3dB增加,并且途径是有效的。
简介:Yttriumaluminumgarnet(YAG)transparentceramicswerefabricatedbysinteringatoxygenatmosphere.Tetraethylorthosilicate(TEOS)wasaddedasthesinteringadditivetocontrolthegraingrowthanddensification.Poreswereeliminatedclearlyattemperaturelowerthan1700oC,whilegrainsizewasaround3μm.Thein-linetransmittancewas80%at1064nmwhensamplesweresinteredat1710oC.TheeffectofTEOSwasstudiedinoxygenatmospheresinteringforNd:YAGtransparentceramics.Athighertemperaturelike1710oC,thegraingrowthmechanismwassolutedrag,whileat1630and1550oCthegraingrowthwascontrolledbyliquidphasesinteringmechanism.And0.5wt.%TEOSwasthebestaddingcontentforNd:YAGsinteredinoxygenatmosphere.
简介:Itisexpectedthatinthenewcentury,tocopewithdevelopmentsofnewhightemperaturetechnologies,anewgenerationofhighperformancerefractoryceramicswillemergeandflourishwhichshouldincludethefollowing(1)oxideandnonoxidecompositescharacterizedbyauniquecombinationofhighhotstrength,highthermalshockresistanceandhighcorrosionresistance;(2)freeCaObearingbasicrefractoriescapableofpurifyingmoltenmetalforimprovingcleanlinessandofabsorbingcontaminantsfromwastegasesforreducingenvironmentalpollution;(3)freeflowingzerocementcastableswithimprovedthermomechanicalproperties,thermalshockresistanceandcorrosionresistanceandgradientcastableswithvaryingmatrixcompositionandvaryingtexture.
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简介:ZhengzhouUniversityniversitiesinChinaandisoneofthenationalkeyuisjointlysupportedbytheMinistryofEducationandHenanProvincialGovernment.ItislocatedinZhengzhoucity,capitalofHenanprovinceincentralChinawhichisthecradleofChineseculture.Theuniversitycampuscoversanareaof4.3millionm2.Thereare40thousandundergraduateand3600post-graduatestudents.Itsceramicsdepartmentenrollsabout350students.
简介:Macroporoussiliconnitride(Si3N4)ceramicswithhighstrength,uniformstructureandrelativelyhighporositywereobtainedbygelcastingandcarbonthermalreactioninatwo-stepsinteringtechnique.Microstructureandcompositionwereinvestigatedbyscanningelectronmicroscopy(SEM),transmissionelectronmicroscopy(TEM),X-raydiffraction(XRD).Openporosity,poresizedistributionandbasicmechanicalperformanceweremeasuredbyArchimedesmethod,mercuryintrusionporosimetryandthree-pointbendingmethods,respectively.SEMandTEMresultsrevealedthatporeswereformedbyelongatedβ-Si3N4.SADPmeasurementprovedtheformationofSiCparticles.TheSiCgranuleswerebeneficialfortheformationofhighratioelongatedβ-Si3N4,andatproperamount,theyalsoactedasreinforcementphase.Thermodynamicanalysisindicatedthatthemechanismsofthereactionsweremainlyassociatedwithliquid-solidreactionandgas-liquidreaction.
简介:DopedSrTiO3capacitor-varistormultifunctionalceramicswerefabricatedbyasinglesinteringprocess.ACcompleximpedanceanalysiswasperformedtoinvestigateelectricalfeaturesofgrainsandgrainboundariesforbothas-reducedceramicandreoxidizedceramics.Theresultsshowedthattheas-reducedceramicexhibitedinductiveresponseathighfrequenciesabove2MHz,whichisattributedtothecontributionofelectronbehaviorinsemiconductinggrains.Thehighfrequencyinductiveresponsedisappearedinimpedanceplotsofreoxidizedceramics.
简介:以便在oxyfluoride眼镜和玻璃陶艺的形成上调查不同重金属离子的影响,有不同PbF2/CdF2比率的样品被融化熄灭和热处理方法准备了。玻璃网络结构上的Pb2+和Cd2+的不同效果被FTIR和拉曼系列调查。在玻璃网络结构的形成期间,Pb2+喜欢打破Si–O–Si契约并且随后为起诉赔偿结合到F−,并且Cd2+喜欢打破Si–O–Al契约并且被O2−包围。Pb2+和F−一起聚在一起并且形成氟化物nanocrystals,当Cd2+在热处理以后留在氧化物矩阵时。合适的CdF2的介绍是重要的在透明玻璃陶艺的制造调整并且控制玻璃网络结构和结晶化过程。