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简介:ItwasgenerallyconsideredthatcontaminationofthegeltypepolystyrenestrongbasicanionexchangeresinbyorganicmatterinnaturalwateristheresultofionexchangeandVanderwaal′sadsorptiononit.Onthebasisoflaboratoryandindustrialexperiments,thispaperconfirmedthattheinterreactionbetweenorganicmatterandresinpolymermatrixisprimarilycontroledbyaVanderwaal′sadsorption.
简介:Four1,2,3-trisubstitutedimidazoliniumiodideswhichwereusedas5,10-+CPh-THFmodel(7-10)atformicacidoxidationlevelweresynthesized.Thebenzylidynegroup(phenyl-substitutedonecarbonunit)transferreactionsfromthesecompoundstoGrignardreagentwerein-vestigated,andthereactionsofthesecompoundswithKBH4andNaOHwerealsostudied.
简介:利用蒙特卡罗模拟程序MCNP研究了NaI(Tl)探测器对海水中137Cs、131I的比计数率响应情况;计算了NaI(Tl)探测器对不同半径海水球体源中137Cs与131I的比计数率响应曲线;分析了探测器防水套筒、NaI(Tl)晶体尺寸与结构、射线能量等因素对比计数率响应的影响;拟合了3R3型、5R5型NaI(Tl)探测器最大比计数率ymax及有效探测距离D。防水套筒模型与裸晶体简化模型的计算结果对比表明,裸晶体模型会给计算带来明显的偏差,应在模型设计时,考虑探测器结构,构建更精确的模型。
简介:FiveC3/C3fluoroquinolonedimerstetheredwithafusedheterocyclicringofs-triazolo[2,1-b][1,3,4]thiadiazolederivedfromantibacterialquinolonesweresynthesizedandcharacterized,andtheirinvitroantitumoractivityagainstL1210,CHOcelllineswasevaluatedviatherespectiveIC50values.
简介:Temperature-dependentphotoluminescencecharacteristicsoforganic-inorganichalideperovskiteCH3NH3PbI3-xClxfilmspreparedusingatwo-stepmethodonZnO/FTOsubstrateswereinvestigated.Surfacemorphologyandabsorptioncharacteristicsofthefilmswerealsostudied.Scanningelectronmicroscopyrevealedlargecrystalsandsubstratecoverage.Theorthorhombic-to-tetragonalphasetransitiontemperaturewas140K.Thefilms’excitonbindingenergywas77.6±10.9meVandtheenergyofopticalphononswas38.8±2.5meV.TheseresultssuggestthatperovskiteCH3NH3PbI3-xClxfilmshaveexcellentoptoelectroniccharacteristicswhichfurthersuggeststheirpotentialusageinperovskitebasedoptoelectronicdevices.