简介:微隧道通常在0.3nm的范围与孔指矿物质的结构的隧道到2.0跑。如此的微隧道包括,K在cryptomelane充满的Mn-O八面体隧道,和Si-O和Al-0四角形的分子的筛构造的隧道在沸石由Na和Ca充满了,并且有效地有分子的筛的功能。这里,我们指出自然矿物质的ultra-microchannels与离子的筛的特征在0.3nm下面有孔。矿物质长石的ultra-microchannels,为地球的半团的财务“scrust,因为孔是太小的,大部分被忽略了。在这个工作,我们在场那长石显示离子交换的某个度并且在高、低的温度下面拥有隧道结构的一个特征。在高温度,Na~+能进入长石的隧道。在直到15.9%的长石增加的Na_-O的Thecontent。在中间的温度,Pb~(2+)能也作为离子交换的结果进入长石的隧道,这样带到形成ofPb长石。在房间温度,大约97.94%Cd~(2+)能被移开,Cd长石能被获得。这些现象显示长石的ultra-microchannels的典型效果,它可以为重金属污染和原子废物的处理作为一个潜力被建议。自然矿物质的Theultra-microchannels在移植和交换ofgeomaterials起了特殊作用。一些自然矿物质的微隧道的分子的筛有净化分子的煤气的污染的性质。并且很自然的矿物质的ultra-microchannels的离子的筛能净化离子的水污染。
简介:ThispaperpresentsthefirstspecificstudyoftheTh-andU-bearingminerals,whichwererecentlyfoundintheSEMediterraneanmarginofSpain(ElHoyazoarea,Almeriaprovince).ThesemineralsareREEphosphates(mainlymonazite)whichoccurasamoeboidal-to-elongateinclusions,fromaround10120μmto120μm,hostedinsinglegarnetcrystalsfromdacitelavasandmetamorphicrocksfromtheElHoyazoVolcanicComplex.ThandUcontentsarehigherthan1wt%,with3.04to5.62wt%forTh02,and0.7to1.75wt%forUO2.Bothelementsarealsofoundinxenotime(ThO2:0.24,UO2:0.27wt%).Giventhattheerosionofthevolcanicsourcerockshasgenerateda“placer-type”depositofmonazitesandsandthatgarnets(maincarriersofmonazite)arebeingcommercialised,anenvironmentalmonitoringandmanagementplanshouldbeurgentlyexecutedinthearea.
简介:Tungstenminerals(scheeliteandwolframite)fromtwogenetictypesofgranitoidsshowsignificantdif-ferencesinREEdistribution,probablyduetodifferentmaterialsourcesandorigins.Tungstenminer-alsingraniteporphyryofthecrust-mantlesourcearerelativelyhighin∑REE(1884ppmonaverage).∑Ceisrichrelativeto∑Yand∑Ce/∑Yisrelativelyhigh(>1).Thechondrite-normalizedREEdistributionpatternsarecharacterizedbyagroupofrightward-inclinedcurves.Tungstenmineralsinquartzveinsintrudingthegranitesofcrustoriginhavelower∑REE(335ppmonaverage).∑Yisrichrelativeto∑Ceand∑Ce/∑Yisrelativelylow(<1).Thechondrite-normalizedREEdistributionpatternsarecharacterizedbyagroupofleftward-inclinedcurves.SotheREEdistributionpatternscanbeusedtodiscriminatethesourcesofrock-andore-formingmaterialsandthegenetictypesofWdepositssoastoprovidecluestooreprospecting.
简介:克莱矿物质能在土壤和含水土层妨碍各种各样的沾染物的运输,但是泥土矿物质怎么在含水土层影响nanoparticles的运输,没深入地被调查。在这份报纸,表面活化剂的运输在明确的石英沙驱散多围的碳nanotubes(MWCNT),有改变离子的力量的石英沙和泥土矿物质(kaolinite和montmorillonite)的混合物被学习。钠dodecylbenzenesulfonate(SDBS)和MWCNT暂停能容易通过石英沙移植的octyl-phenol-ethoxylate(TX100),而是在石英沙罐头的不到2%w/w泥土矿物质的存在显著地妨碍MWCNT暂停的运输,特别在高离子力量(0.6公里CaCl2)。为在多孔的媒介的分散表面活化剂的MWCNT的泥土矿物质的抑制机制是MWCNT的拦截。因为更多的kaolinite能在石英沙被保留,Kaolinite比montmorillonite为MWCNT运输有更强壮的抑制效果。由泥土矿物质的表面活化剂的吸附不显著地影响MWCNT的运输。这发现为对在土壤和含水土层的MWCNT运输风险的环境评价是重要的。
简介:Dryseparationofironmineralfromlow-gradecoal-serieskaolininHubeiProvinceofChinawasinvestigated.ThestructureandchemicalcompositionofthekaolinoreweredeterminedbyX-raydiffraction(XRD)andX-rayFluorescence(XRF)analyses.Thenarrowparticlesizerangeclassification,drymagneticseparationandcalcinationwerecarriedouttoevaluatetheparticlesizedistribution,andtherelationbetweenthecontentofironandthewhiteness.Experimentalresultsrevealedthatthehighestcontentofiron(3.70%)inkaolinorewasintheparticlesizerangefrom60to74μm,andpyritewasthemainoccurrenceofironinthekaolinore.Drymagneticseparationshowedthattheremovalrateofironinkaolinorecouldbeincreasedobviouslyaftercalcination,andtherateofironremovalwas60%intheparticlesizerangefrom60to74μm.Aspyritecanbetransformedintohematitethroughcalcination,thermodynamicstudiesandXRDanalysisshowedthatthemaximumcontentofhematitewasobtainedat900℃,whichwouldbemorebeneficialtomagneticseparation.
简介:Thecomposition,assemblageanddistributioncharacteristicsofheavymineralsfrom63to125μmgrainsizesinsurfacesedimentfromtheXinghuaBay(17stations)arestudied.Themattersourceofsiltandtherelationshipbetweenheavymineralsandsedimentaryenvironmentarealsodiscussed.Theresultsshowthatthereare37kindsofheavymineralsandtheaveragecontentofthemis12.08%,whichexceeds6%comparedwiththeMeizhouBay(5.67%).Thedominantmineralsaremagnetite,hornblende,epidote,ilmenite,hematite,limonite,zirconandsoon.MineralkindsrevealthatthesourcesofsiltinthisbayarethefluvialinputanderodedproductsofbedrockincircumjacentlandandislandsoftheXinghuaBay.However,themattersourcefromoutsidethisbayisless.FourmineralassemblagezonescanbedividedbasedonheavymineralcontentsanddistributioncharacteristicsintheXinghuaBay,whicharenotonlyinfluencedbymattersource,butalsocontrolledbyhydrodynamicconditionandsedimentaryenvironmentintheXinghuaBay.
简介:Inthispapertheseven-stepcontinuousextractingmethodwasemployedinthestudyofchemicalformsofthesixheavymetalsCo,Zn,Pb,Cu,CrandMn,Theresultshowsthattheetalsinthelateritearepresentinthechemicalformofcrystallineironoxidesandresidues,andtheyaretransformedtowaredorganicandexchangeableformsinthesurfacesoil.Linearregressionanalysisindicatesthattheaboveheavymetalshaveapositivecorrelationwiththecrystallineironoxideminerals.Thecrystallineironoxidemineralshaveaveryimportantroletoplayintheenrichmentofheavymetals,especiallythesolidcomponentsinthelaterite.
简介:Chinahaslongbeenrecognisedasanimportantsourceofrefractoryrawmaterialsforrefractorymarketsworldwide.Bauxite,magnesia,fusedalumina,andrefractoryclaysinparticular,havemaintainedChina'sstrongpositionastheworld'sleadingsupplieroftheseminerals.However,importantchangeshavetakenplaceirthestructureofChineseandglobalsupplyoftheseminerals.Moreover,theworldrefractorymarketandthemineralstradingsectorhavealsoundergonearadicaltransformationthathasinfluencedmineralsupply,andshiftedendproductmanufacturetoChina.ThispaperhighlightsthesechangesandseeshowtheyhaveimpactedonChinaasaworldsourceofrefractoryminerals.
简介:Inorganic-richgasshales,claymineralsandorganicmatter(OM)havesignificantinfluencesontheorigin,preservation,andproductionofshalegas.Becauseofthesubstantialroleofnanoscaleporesinthegeneration,storage,andseepageofshalegas,weexaminedtheeffectsofclaymineralsandOMonnanoscaleporedistributioncharacteristicsinLowerPaleozoicshalegasreservoirs.UsingtheNiutitangandLongmaxishalesasexamples,wedeterminedtheeffectsofclaymineralsandOMonporesthroughsedimentationexperiments.Fieldemission–scanningelectronmicroscopycombinedwithlow-pressureN2adsorptionofthesamplesbeforeandaftersedimentationshowedsignificantdifferencesinporelocationandporesizedistributionbetweentheNiutitangandLongmaxishales.NanoscaleporesmostlyexistedinOMintheLongmaxishaleandinclaymineralsorOM–claycompositesintheNiutitangshale.Thedistributiondifferenceswereattributedlargelytovariabilityinthermalevolutionandtectonicdevelopmentandmightaccountforthedifferenceingas-bearingcapacitybetweentheNiutitangandLongmaxireservoirs.Inthenanoscalerange,mesoporesaccountedfor61–76%oftotalnanoscaleporevolume.ConsiderablydevelopednanoscaleporesinOMweredistributedinabroadsizerangeintheLongmaxishale,whichledtogoodporeconnectivityandgasproduction.Numerousnarrowpores(i.e.,pores\20nm)inOM–claycompositeswerefoundintheNiutitangshale,andmightaccountforthisshale’spoorporeconnectivityandlowgasproductionefficiency.Enhancingtheconnectivityofthemesopores(especiallypores\20nmandthosedevelopedinOM–claycomposites)mightbethekeytoimprovingdevelopmentoftheNiutitangshale.ThefindingsprovidenewinsightintotheformationandevolutionarymechanismofnanoscaleporesdevelopedinOMandclayminerals.
简介:ApotassiumsolubilizingbacterialstraindesignatedEGT,whichistolerantofhightemperature,wasisolatedfromanearthworm’sguttoobtainabacteriumthatcanweatherpotassium-bearingrockeffectivelythroughsolid-statefermentation.Molecularphylogenyand16SrRNAgenesequenceanalysisdemonstratedthebacterialstrainwasamemberoftheStreptomycesgenus.Toassessitspotentialtoreleasepotassiumfromsilicateminerals,thisstrainwasusedtodegradepotassium-bearingrockpowderbysolid-statefermentation.Afterfermentation,theamountofwater-solubleAl,FeandKofthesubstratewithactiveinoculumwashigherthanthoseofthecontrol,whichhadautoclavedinoculum,andthoseofthefreshsubstrate.Theresultindicatedthatthestrainhadtheabilitytoweatherpotassium-bearingrockandcouldbeusedasaninoculumintheproductionofpotassiumbio-fertilizer,duetoitspotassiumreleaseactivityfromrockandtolerancetohightemperature.
简介:Hydrocarbonmicro-seepagecancauseoxidationreductionreactionsandproducealteredmineralsinsurfacesedimentsandsoil.Thetypicalalteredmineralsmappingbytheirdiagnosticspectralfeaturesonhyper-spectralimagesisanimportanttoolforthepetroleumexplorationindustry.Inthisstudy,theairbornehyper-spectraldatawereusedtoinvestigatethealteredmineralsinducedbyhydrocarbonmicro-seepagesbyspectralfeaturefitting(SFF)intheloesscoverageareaofXifengOilfield.Theresultsrevealthatthedistributionregionofthealteredmineralsinducedbyhydrocarbonmicro-seepageislargerthantheknownoilfieldexplorationarea.Thepotentialhydrocarbonmicro-seepageregionwasalsorevealedbythedistributionofalteredmineralsbesidestheknownhydrocarbonarea.Afastindexwasproposedbytheabsorptiondepthsofclayandcarbonatemineralsforassessmentofhydrocarbonmicroseepage.Anditgavemuchclearerboundariesforthehydrocarbonmicro-seepageintheloesscoverageareathanthosebythealteredmineralmapping.Inaddition,somefieldsampleswereanalyzedbyX-raydiffraction(XRD)andatomicabsorptionspectrophotometertovalidatetheresults.Withintheextentsofhydrocarbonmicro-seepage,therearelowercontentsofferricironandhighercontentsofcarbonatemineralsinthesesamples.Therefore,itissatisfactorytohavetheairbornehyper-spectraldatatooutlinetheextentsofhydrocarbonmicro-seepageforfurtherhydrocarbonexplorationintheloesscoveragearea.
简介:TheadsorptionkineticsofPb^2+ondifferentsoilsandmineralswithvariablechargeswasstudiedbythetwoion-selectiveelectrodetechniqueatdifferentpHandconcentrations.Theresultsshowedthatmorethan95%ofadsorptiononallthesamplesoccurredduringthefirst5minutes.Alladsorptiontime-dependentdatacouldfitthesurfacesecond-orderequationverywell.ThevaluesofXmweregoethite>kaolinite,andlatosol>redsoilatthesameinitialreactionconcentration.Thevaluesofkwerekaolinite>>goethite,andlatosol>redsoilatthesamereactionpHandinitialconcentration.ThehigherthesuspensionpH,thefastertheadsorptionoccurred.ThemeaningofXmgotbythetwoion-selectiveelectrodetechnique(onekindofbatchtechnique)wasdifferentfromthatbythemiscibledisplacementtechniqueinthattheformerwasonlytheequilibriumadsorptionamountatadefiniteconcentrationandpH,butthelatterwasalmostequaltotheadsorptioncapacityatadefinitepHwithmuchlessinfluenceofconcentration.OnePb^2+wassupposedtooccupytwoadsorptionsitesastheadsorptionmechanismisconcerned.