简介:Glasseswiththecompositionof65GeO212Ga2O3-10BaO-8Li2O-5La2O3(molarratio)dopedwith1.526wt.%,3.006wt.%,5.836wt.%,11.028wt.%,and15.678wt.%Tm2O3,respectively,werefabricatedbyconventionalmeltingmethod.AccordingtotheabsorptionspectraandtheJudd-Ofelttheory,theJ-Ostrengthparameters(Ω2,Ω4,Ω6)werecalculated,withwhichtheradiativetransitionprobabilities,branchingratiosandradiativelifetimeswereobtained.Theinfraredemissionspectra(with808nmLDexcitation)at~1.47and~1.8μmofvariousconcentrationsofTm3+-dopedglasseswerestudied.Theemissionintensityat~1.8μmreachedtothemaximumwhentheTm2O3-dopingconcentrationwasneartobe~3.006wt.%(1.0mol.%),andthendecreasedasdopingconcentrationincreasedfurther.Themechanismofthefluorescenceintensitychangewasexplainedwiththecross-relaxationeffectandtheconcentrationquenchingeffectofTm3+.Meanwhile,accordingtoMcCumbertheory,theabsorptionandemissioncross-sectionscorrespondingtothe3F4→3H6transitionsofTm3+at1.8μmwasobtained.ForTm3+-dopedgermanateglasses,themaximumemissioncross-sectionreachedavaluehigherthanthatre-portedforfluorozircoaluminateglasses.Itisexpectedtobeafavorablecandidatehostfor~2.0μmmid-inflatedlaserbecausetheglassshowsfavorableopticalspectra.
简介:Baosteel's60000m3/hairseparationunit(ASU),thefirstdomestically-integratedunitofitsclass,isamilestoneintheChineseairseparationindustry.Inthispaper,theprocesscharacteristicsoftheunitandtheapplicationoftheoriginaltechniquesareexpatiated.Somedifficultiesintheprocessdesign,theriskcontrol,thequalitycontrol,thecontrolsystemintegrationandthesystemcommissioningareanalyzedandappraised.Themodeoftheprojectintegrationandinnovation,thecooperationamongindustriesandtheuser-orientatedprojectmanagementmodeareintroduced.Finally,thesuccessfulexperiencesininnovationaresummarizedwiththefocusontheintegrationoftheproject.
简介:AdetailedstudyofthefluorescenceemissionpropertiesandenergytransfermechanisminEr3+/Tm3+co-dopedleadsilicateglasseswasreported.Enhancednearinfrared1.8μmandvisibleup-conversionemissionswereinvestigatedunder808and980nmexcitations,respectively.TheenergytransfermechanismbetweenEr3+andTm3+wasanalyzedaccordingtotheabsorptionspectra,theemissionspectraandthelevelstructuresofEr3+andTm3+.TheenergytransferefficiencybetweenEr3+andTm3+reached68.1%intheEr3+/Tm3+co-dopedleadsilicateglasseswhenpumpedby808nmlaserdiode.Basedontheabsorptionspectra,theJudd-Ofeltparameters,spontaneousemissionprobability,absorptionandemissioncrosssections,gaincoefficientswerecalculatedandanalyzed.Itwasfoundthatthecalculatedemissioncrosssectionandthemaximumgaincoefficientaround1.8μmwere4.9×10–21cm2and1.12cm–1,respectively.TheseresultsindicatedthattheEr3+/Tm3+co-dopedlead-silicateglasseshadpotentialapplicationinnearinfraredlasers.