学科分类
/ 10
183 个结果
  • 简介:FluorescencespectraofSm2+andEu2+→Sm2+energytransferwerestudiedinSrB4O7.Thereappearsonlyfluorescencefrom5D0transitionofSm2+at77K.Thevibroniclinesassociatedwith5D0→7F0transitionwereobserved.Thethermalpopulationtoupperstatesof5D1and4f5dlevelsfrom5D0givesriseto5D1→7FJand5d→4fradiativetransitionsofSin2+athighertemperature.

  • 标签: Strontium-samarium BORATE Energy transfer ELECTRON-PHONON interaction
  • 简介:文章研究了对Mg-9Gd-4Y-0.6Zr合金在时效过程中的微观组织。在225℃时效初期硬度缓慢上升,之后硬度急剧上升,24h出现了明显的时效硬化峰,然后硬度开始下降。微观结构的分析结果表明,在初期(2h)产生了大量弥散分布的具有DO19结构的β″,而在峰值时(24h)出现具有bco的β′,在持续时效(384h)时出现亚稳相β1,而在后来的长时间时效(1000h)时出现既在原位转变的平衡相β。

  • 标签: Mg-9Gd-4Y-0.6Zr合金 时效硬化 沉淀相 微观组织
  • 简介:Sr1.995–1.5xGdxSiO4:0.005Eu2+phosphorserieswithx=0–0.08molfornear-ultravioletwhitelight-emittingdiodes(NUVw-LEDs)weresynthesizedviasolid-statereactionmethod.XRDprofilepatternandrefinementresultsdemonstratedthatdopingGd3+ionsresultedinthephasetransformation(β-Sr2SiO4→α’-Sr2SiO4).Thephotoluminescencespectrumofthesamplewithx=0moldisplayedtwoemissionpeakscenteredat470and525nm.Thetwo-peakspectrabecameone-peakspectrawiththeGd3+concentrationincreasing.Actually,thefittingresultsdemonstratedthattheone-peakspectrawerestillcomposedoftwosingleemissionspectra.ThephotoluminescenceintensitywasimprovedandtheCIEchromaticitycoordinateswereadjustedviadopingGd3+.

  • 标签: 过掺杂 荧光粉 Gd 发光性能 晶体结构 紫外发光二极管
  • 简介:工信部日前对外发布,2016年,规模以上工业增加值能耗同比下降5.47%、单位工业增加值用水量同比下降6%,节能环保产业同比增长10%,圆满完成了年度目标任务。

  • 标签: 节能减排 增加值 工业 能耗 同比增长 环保产业
  • 简介:Organicsubstancesuchassolventandresin'seffectonluminescentcapabilityofSrAl2O4:Eu2+,Dy3+phosphorwasstudied.Someorganicsolventsandresinswereselectedforexperimentation.TheresultsindicatethatthoseorganicsolventswillnothavenegativeeffectontheappliedcapabilityofSrAl2O4:Eu2+,Dy3+phosphor.Adoptingtheorganicresinsandcoveringmethod,theafterglowluminanceofSrAl2O4:Eu2+,Dy3+phosphorwasincreasedby85.01%and82.51%.

  • 标签: ORGANIC solvent ORGANIC RESIN effect LUMINESCENT
  • 简介:Er3+-Tm3+-Yb3+tri-dopedBaMoO4phosphorsweresynthesizedbyco-precipitationtechniqueandcharacterizedbyX-raydiffractionanalysis,absorptionstudyandfieldemissionscanningelectronmicroscopyanalysis.Upconversionaswellasdownconversionluminescencestudieswereperformedbyusingnearinfrared(980nm)andultraviolet(380nm)excitations.Energyleveldiagram,pumppowerdependenceandcolourcoordinatestudywereutilizedtodescribethemulticolorupconversionemissionproperties.Undersingle980nmdiodelaserexcitationthedualmodesensingbehaviourisrealizedviaStarksublevelsandthermallycoupledenergylevelsoftheTm3+andEr3+ionsinthepreparedtri-dopedphosphors.AcomparativefluorescenceintensityratioanalysisforintegratedemissionintensitiesarisingfromtheStarksublevels{1G4(a)and1G4(b)}andthermallycoupledenergylevels{2H11/2and4S3/2}oftheTm3+andEr3+ions,respectivelywascarriedoutinthepreparedtri-dopedBaMoO4phosphors.ThemaximumsensitivityforthermallycoupledenergylevelsoftheEr3+andStarksublevelsoftheTm3+ionwasreported.Thedevelopedphosphorscouldbeusefulinthedisplaydevicesandopticalthermometricapplications.

  • 标签:
  • 简介:RE-dopedNi-basedcatalystswerepreparedbysol-gelmethod.ThesecatalystswereappliedtothereactionofCO2reformingCH4tosyngas.ThestudiesrevealthatRE-doped(RE=La,Ce,Sm,Yb)Ni-basedcatalystsshowhighercatalyticactivitythanundopedNi-basedcatalyst,andwiththeincreasingofRE-dopedquantity,thecatalyticactivityofcatalystsexhibitsregularchanges.WhenRE-dopedquantityis0.2%(molarratio),thecatalystsshowthebestcatalyticactivity.

  • 标签: DOPE BATIO3 CATALYST RARE earths
  • 简介:卢本巴希8月30日消息:刚果国家矿业公司表示,2年内该公司将把铜产量提升一倍至4万吨左右。预计2006年该公司的铜产量将提升至2.2万吨左右,此前几年产量均下降。公司表示:“产量正处于上升趋势。我们希望在两年生产3万吨,甚至可能达到4万吨。”www.cnitdc.com

  • 标签: 矿业公司 年产量 刚果 上升趋势
  • 简介:ThestructureandhydridingperformanceofLa0.6Nd0.4Ni4.8Mn0.2Cux(x=0~0.4)alloyswereinvestigatedinordertodevelopsuitablematerialsformetalhydrideairconditioner.TheeffectofCuadditiononthecrystalstructure,equilibriumpressure,hydrogencapacityandhysteresisaswellashydrogenabsorption/desorptionkineticsweresystematicallystudiedbyusingthemeasurementofP-Cisotherms,X-raydiffractionandscanningelectronmicroscopy.AstheamountofCuincreases,theplateaupressureincreasesandhydrogenabsorption/desorptionkineticsisimproved,buttheeffectivehydrogenstoragecapacitydecreases.Itisshownthatvariationsinthebasalplaneparameteracanbeusedasanindicationfortheplateaupressurechanges.Withtheincreaseofparametera,theplateaupressuredecreases.ForLa0.6Nd0.4Ni4.8Mn0.2Cux(x=0~0.4)alloysthereisarelationshipbetweentheeffectivehydrogenstoragecapacitiesandtheratiosoftheirunitcellparameterscanda.Theeffectivehydrogenstoragecapacitydecreaseswithincreaseofa/c.

  • 标签: metal HYDRIDE crystal structure HYSTERESIS KINETICS
  • 简介:有一致形态学的新奇红射出的K2(Ge,Si)F6:Mn4+黄磷被一起沉淀方法综合。纯K2有P636阶段>除P3m1空间组以外的mc空间组就被Si的加入在K2在房间温度的GeF6根据XRD描述。薄片状的显示出的SEM图象和为K2GeF6:Mn4+和K2(Ge,Si)F6:Mn4+黄磷分别地。光致发光刺激(PLE)和光致发光(PL)在K2GeF6:Mn4+和K2(Ge,Si)F6:Mn4+系统。并且K2有Si的GeF6:Mn4+显示出一座强壮的山峰。同时水晶的地包围Mn4+变化能在这个氟化物系统影响腐烂时间。带的设备的颜色范围基于K2(Ge,Si)F6:Mn4+和K2分别地,GeF6:Mn4+到达了多达94.58%NTSC(国家电视标准委员会)和94.386%NTSC那基于氮化物红黄磷比那高得多。在K2(Ge,Si)F6:Mn4+黄磷的所有这些原来的特征作为为改善灯光和常规白LEDs的显示质量的红黄磷为潜在的应用是合乎需要的。

  • 标签: 红色荧光粉 白光LED SI Ge 发光性能 合成
  • 简介:PolycrystallineGd2(MoO4)3:Dy3+phosphorshavebeensynthesizedbyhightemperaturesolid-statereactionmethod.ThephosphorswerecharacterizedwithX-raydiffractometer,thermogravimetricanalysisanddifferentscanningcalorimeter,scanningelectronmicroscopy,andphotoluminescencespectrofluorimeter.Severalpeaksat351,389,425,452,and472nmappearedinphotoluminescenceexcitationspectrum,whichmatchedwellwiththeemissionoftheultraviolet(UV)andblue-lightemittingdiode(LED)chips.Uponexcitationat389nmUVlight,intenseemissionscenteredat484,575and668nmwereattributedtothetransitionsof4F9/2→6H15/2,4F9/2→6H13/2and4F9/2→6H11/2ofDy3+,respectively.ThechromaticitycoordinatesandcorrelativecolortemperatureshavebeencalculatedandpresentedintheCommissionInternationaldeI'Eclairage(CIE)diagrams.TheresultsindicatedthatGd1.9(MoO4)3:Dy0.13+withCIEcoordinatesof(x=0.38,y=0.41)andthecorrelativecolortemperatureof4134KisapotentialcandidateforwhiteLEDs.

  • 标签:
  • 简介:铟生产废水中含锌砷镉杂质较高,且含有机物的酸性溶液。铟生产废水处理过程中,首先用纯碱中和废水,至pH值为8左右,大部分杂质沉入中和渣中;然后用硫酸亚铁和双氧水净化,废水达到国家工业排水一级标准。废水处理后进行了回用,实现了零排放,锌富集到中和渣,回收利用。处理过程没有废气产生,工序简单,安全环保。

  • 标签: 废水 中和 净化 回收 环保
  • 简介:(Y,Gd)BxV1-xO4-x:Eu3+phosphorswerepreparedbysolidstatereaction.Theredemissioncolorpurityof(Y,Gd)BxV1-xO4-x:Eu3+phosphorismuchbetterthanthatoftherecentwidely-usedcommercialredemittingphosphor(Y,Gd)BO3:Eu3+anditsrelativeemissionintensityis84%ofthecommercialphosphor(Y,Gd)BO3:Eu3+.Itisexpectedthat(Y,Gd)BxV1-xO4:Eu3+phosphorwillbeapromisingcandidateforPDP(plasmadisplaypanels)application.

  • 标签: PDP (Y Gd)BxVi-xO4-x:Eu3+ PHOSPHOR photoluminescence rare
  • 简介:ThereactionofNdCl3withlithiummethylnaphthalenein1:2moleratioinTHFgeneratesblackpowder.Thepowderreactswithcyclooctatetraene(COT)inTHFtoformthetitlecomplex.[Li(THF)4Nd(C8H8)2]·2THFcrystallizesinthemonoclinicspacegroupP2/cwithunit-celldimensionsa=1.7858(7)nm,h=1.3243(4)nm,c=1.8086(6)nm.β=106.52(4)°,V=4.10nm3andDc=1.268g/cm3forZ=4.F(000)=1660,R=0.0774,Rn=0.0733.Thecomplexconsistsofdiscreteion-pairandtwoTHFmoleculesadduct.Intheanion,theneodymiumatomiscoordinatedbytwoCOTrings.ThestructureofthecationshowsthatthelithiumatomisattachedwithTHFmoleculesonly.

  • 标签: CRYSTAL STRUCTURE ND Cyclooctatetraene
  • 简介:Tobreakthroughthebottle-neckofquantumyieldinupconversion(UC)core-shellsystem,weelucidatedthattheenergytransferefficiencyincore-shellsystemhadanevidentcontributionfromthechargetransferofinterfacewithrelatedtotwofactors:(1)bandoffsetsand(2)bindingenergyareadensity.Thesetwovariablesweredeterminedbymaterialintrinsicpropertiesandcore-shellthicknessratio.Wefurtherunraveledthemechanismofnon-radiativeenergytransferbychargetransferinduceddipoleattheinterface,basedonaquasi-classicalderivationfromF?rstertyperesonantenergytransfer(FRET)model.Withstablebondingacrosstheinterface,thecontributionsonenergytransferinbothradiativeandnon-radiativeenergytransfershouldalsobeaccountedtogetherinAuzel'senergytransfer(ETU)modelincore-shellsystem.Basedonthediscussionaboutinterfacebonding,bandoffsets,andformationenergies,wefiguredoutthesignificanceofinterfacebondinginducedgapstates(IBIGS)thatplayedasignificantroleforinfluencingthechargetransferandradiativetypeenergytransfer.Theinterfacebandoffsetswereakeyfactorindominatingthenon-radiativeenergytransfer,whichwasalsocorrelatedtocore-shellthicknessratio.Wefoundthattheenergyareadensitywithrelatedtocore/shellthicknessratiofollowedthetrendofBoltzmansigmoidalgrowthfunction.Bythephysicaltrend,thisworkcontributedareferencehowthemulti-layeredcore-shellstructurewasformedstartingfromtheverybeginningwithinminimumsize.Aroutewaspavedtowardsasystematicstudyoftheinterfacetounveiltheenergytransfermechanismincore-shellsystems.

  • 标签: 界面结合 核壳结构 发光材料 壳模型 非辐射能量转移 形成能