THE HYDROSILATION REACTION OF LADDERLIKE POLYALLYLSILSESQUIOXANE (ALLYL-T) AND POLYHYDROSILSESQUIOXANE (H-T)

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摘要 Theoneplusone(1+1)modeofhydrosilationreactionofladderlikecis-isotaticpolyallylsilsesquioxane(AllyI-T)andpolyhydrosilsesquioxane(H-T)usingdicyclopentadienylplatinumdichloride(Cp2PtCl2)asthecatalystleadstotheformationofanewpolyorganosiloxane(POS).ThepresenceofnanoscaletubularstructureintheproductPOSwaspreliminarilyprovedbyIR,1H-NMR,differentialscanningcalorimetry(DSC),X-raydiffraction(XRD),gelpermeationchromatography(GPC),atomicforcemicroscopy(AFM)andmolecularsimulation.
机构地区 不详
出版日期 2002年01月11日(中国期刊网平台首次上网日期,不代表论文的发表时间)
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