Theoneplusone(1+1)modeofhydrosilationreactionofladderlikecis-isotaticpolyallylsilsesquioxane(AllyI-T)andpolyhydrosilsesquioxane(H-T)usingdicyclopentadienylplatinumdichloride(Cp2PtCl2)asthecatalystleadstotheformationofanewpolyorganosiloxane(POS).ThepresenceofnanoscaletubularstructureintheproductPOSwaspreliminarilyprovedbyIR,1H-NMR,differentialscanningcalorimetry(DSC),X-raydiffraction(XRD),gelpermeationchromatography(GPC),atomicforcemicroscopy(AFM)andmolecularsimulation.
