简介：黄磷(Bi1-xSmx)2ZnB2O7(x=0.01，0.03，0.05，0.07，和0.09)被常规稳固的州的反应综合。所有样品的纯净被X光检查粉末衍射(XRD)检查。XRD分析证明所有这些混合物具有Bi2ZnB2O7的一个单个阶段，显示在Bi2ZnB2O7的双性人(3+)能被没有晶体结构的变化的Sm(3+)部分代替。在房间温度的刺激和排放系列显示出Sm(3+)的典型4f-4f转变。主导的刺激线在404nm附近由于(6)H5/2→(4)K11/2和排放光谱在563，599，646，和704nm由一系列线组成由于(4)G5/2→(6)H5/2，(6)H7/2，(6)H9/2，并且(6)H11/2分别地。在Bi2ZnB2O7的Sm(3+)的最佳的集中关于3mol%(相对1mol双性人(3+))并且批评距离Rc作为2.1nm被计算。Bi1.94Sm0.06ZnB2O7的排放紧张的温度依赖在在100和450K之间的温度范围被检验。紧张下降了到起始的紧张的一半的熄灭的温度是280K。为在Bi1.94Sm0.06ZnB2O7的Sm(3+)的一生作为0.29和1.03ms的价值被适合。

简介：Differentrareearth(RE)ionsdopantswereaddedintotheSrAl2SiO7:Eu2+phosphorsinordertoenhancethephosphorescenceproperties,andtheeffectoftheREionsincludingYb3+,Ce3+,Nd3+,Dy3+andTm3+,wascomparativelyinvestigated.ItwasfoundthatNd3+additionimprovedthephosphorescencepropertiesobviouslyamongallthestudiedREions.Therefore,Sr1.96–xAl2SiO7:xEu2+,yNd3+phosphorswerestudiedindetail,andtheoptimumEu2+andNd3+concentrationsweredeterminedwiththeafterglowtimeofabout20min.Thephasestructures,photoluminescence(PL)properties,long-lastingphosphorescence(LLP)properties,afterglowdecaycurvesandthermo-luminescence(TL)fortheselectedphosphorsduringthecorrespondingstudywereinvestigated.AllthephosphorsexhibitedgreenPLemissionandLLPemission.ThereweretwoTLbandslocatedatabout325and380Kforthestudiedsamples,andtherelationshipbetweenREadditionandphosphorescencepropertieswasdiscussed.

简介：FluorescencespectraofSm2+andEu2+→Sm2+energytransferwerestudiedinSrB4O7.Thereappearsonlyfluorescencefrom5D0transitionofSm2+at77K.Thevibroniclinesassociatedwith5D0→7F0transitionwereobserved.Thethermalpopulationtoupperstatesof5D1and4f5dlevelsfrom5D0givesriseto5D1→7FJand5d→4fradiativetransitionsofSin2+athighertemperature.

简介：美国宇航局在加州帕萨迪纳的喷气推进实验室研究成功了一种制造YBa2Cu3O7-α高温超导电缆（封装在金属套管内）的新方法。据称,这种方法成本较低,过程易于控制,且对各种前体材料有很强的适应能力。该法分4个步骤:生产具有化学（配）比的前体（Precursor）粉;将前体粉包封在金属套管内;用轧制的方法使前体粉固结;在液态锂金属浴槽内进行处理,使之转变成超导组

简介：LongafterglowphotoluminescentmaterialsSr2MgSi2O7dopedwithEu2+,Dy3+werepreparedbysol-gelmethod.ThesynthesizedsampleswerecharacterizedbyX-raydiffraction.Theexcitationspectrum,emissionspectrumandlongdecaycurveweremeasuredandanalyzed.XRDpatternindicatesthatphosphoriswithSr2MgSi2O7crystalstructure.Thewiderangeofexcitationwavelengthindicatesthatluminescentmaterialcanbeexcitedbylightfromultravioletraytovisiblelight.Themainpeakofemissionspectrumislocatedat466nm.Sampleexcitedbyvisiblelightcanemitbrightbluelight,andtheafterglowtimelastsmorethan8h.

简介：Eu2+andDy3+codoped(Ca,Sr)7(SiO3)6Cl2yellowphosphorsweresuccessfullysynthesizedbyself-fluxmethod.Thestructure,morphologyandphotoluminescencepropertieswereinvestigatedbyX-raydiffraction(XRD),scanningelectronmicroscopy(SEM)andphotoluminescencespectra.Theas-preparedphosphorshowedabroademissionspectrumcenteredat550nmforEu2+single-dopedphosphor,whilelocatedat548–544nmfortheEu2+,Dy3+codopedsamplesunderexcitationat380nmlight.TheemissionintensitywasgreatlyimprovedwhenDy3+wasdopedintothe(Ca,Sr)7(SiO3)6Cl2:Eu2+system.Thecomposition-optimizedsamplewith3mol.%ofDy3+andconstant10mol.%ofEu2+exhibiteda220%PLenhancementcomparedtothephosphorwith10mol.%Eu2+single-doped.Meanwhile,itwasfoundthatthequantumefficiencyofphosphornamely(Ca,Sr)7(SiO3)6Cl2:3mol.%Dy3+,10mol.%Eu2+couldgetupto24.6%.Thesynthesizedyellow-emitting(Ca,Sr)7(SiO3)6Cl2:Dy3+,Eu2+isapromisingcandidateashigh-efficiencyyellowphosphorforNUV-excitedwhiteLEDs.

简介：Awhitelong-lastingphosphorCa2MgSi2O7:Dy3+waspreparedbythesolid-statereaction.Astrongbandpeakedat260nmwasshownintheexcitationspectrumof578nmemission,whichmightbeattributedtotheoxygendeficiencyofthehost.Afterirradiatedwith254nmfor4min,thewhiteafterglowofthesamplecouldbeseenfor3h.Moreover,thedepthsandfrequencyfactorsoftrapcenterswerecal-culatedfromthethermo-luminescencecurveofthesample,whichindicatedthatthetrapcenterscorrespondingtothe414Kbandweremorehelpfultothelong-lastingphosphorescence.

简介：15%Ag-addedcubicperovskitesSr0.9La0.1TiO3andRuddlesden-Popper(RP)phasesSr2.7La0.3Ti2O7werefabricatedviahydrothermalsynthesis,coldpressingandhigh-temperaturesintering.Thestructureandthermoelectricpropertieswerealsoinvestigatedforallsamples.TheresultsindicatedthatAgprecipitatedasasecondphase.AgadditionmadeelectricalconductivityandabsoluteSeebeckcoefficientenhanced,asaresult,theZTvalueswereenhancedbothfortwoseries.Comparedwithcubicperovskite,RPphasewassubjectedtosmallerimpactbyAgaddition.ThereasonsforenhancingZTvalueandthedifferentimpactfortwoseriesbyAgadditionwerealsodiscussed.

简介：

简介：由日本和中国科学家组成的研究组研究了一种新的金属间化合物SmFe7的磁晶各向异性。SmFe7金属间化合物单晶用自助熔法生长,用转矩磁强计测量磁晶各向异性。

简介：在内蒙古包钢稀土高科技股份有限公司的倡议下,部分稀土企业的代表于1999年3月30日在包头举行了第二次稀土产品价格统一协调会。参加会议的有内蒙古包钢稀土高科技股份有限公司、包头市和发稀土开发集团有限责任公司、甘肃稀土公司、江苏溧阳

简介：Loadedonthecordierite,therareearthdopedcompositecatalystwaspreparedbysol-gelmethodcombinedwithdippingtechnique.TakingOrthodichlorobenzeneasmodel,thecatalystwasusedtoremovethedioxinsofthewastegas.Theresultsshowedthatat280℃andgasspacevelocitybeing8000h-1,theorthodichlorobenzenecouldberemovedeffectivilybythepreparedCeO2-TiO2-V2O5compositecatalystwhoseactivitywasremarkablyenhancedbythedopingofCe,whiletheindustrialside-streamtestofdioxinsfromrefuseincinerationsmokeindicatedthatthedecompositionratecouldreachabove93%underthesameconditions.

简介：Inthiswork,boththethermalexpansionandelectricalconductivityofnanocrystallineLa2Mo2O9werestudied.ThenanocrystallinepowderofLa2Mo2O9wasobtainedbysol-gelmethod,andwiththehelpofSHP(superhighpressure)upto4.5×104atmat700℃forashorttime,andthenanocrystallinepowderwasdensifiedwithoutobviousparticlesizegrowth.TheelectricalconductivityofnanocrystallineLa2Mo2O9wasoneorderofmagnitudelowerthanthatofthemicrocrystallinesampleatthesametemperature.Owingtothephasetransition,themicrocrystallineLa2Mo2O9hasanabruptincreaseofthermalexpansionwithapeakvalueof48×10-6K-1at556℃.Forthenanocrystallinematerial,thepeakvalueincreasesto112×10-6K-1at520℃.Ontheotherhand,above600℃thesignificantgrowthofparticlesizeofthenanocrystallineLa2Mo2O9wasobserved,accompanyingbyatremendousincreaseofthermalexpansionwithapeakvalueofthirdhigherthanthatofLa2Mo2O9.

简介：Basedonthethermodynamicallyself-consistentanalysisandoptimizationofthreesub-binarysystemsoftheternarysystemPrCl3-CaCl2-MgCl2,thethermodynamicsofthisternarysystemhasbeenstudied.UsingHillertmodelandtakingMgCl2asanasymmetriccomponent,thePrCl3-CaCl2-MgCl2phasediagramhasbeencalculated.Theagreementbetweencalculatedandmeasuredcompositionsandtemperaturesatdeflectingpointsonliquidusisgood.Thesystemisasimpleeutecticonewithaeutecticpointat26.0mol%PrCl3,41.5mol%CaCl2,32.5mol%MgCl2;560℃（calculated）and26.0mol%PrCl3,39.4mol%CaCl2,34.6mol%MgCl2;546℃（measured）,respectively.

简介：TheZrO2-Al2O3ceramiccompositeswerepreparedbyappropriatetechniqueswithcommercialZrO2andAl2O3powdersasrawmaterialsandY2O3asstabilizer.TheresultsindicatethatwiththeintroductionofAl2O3intotheZrO2matrixwherethequantityofadditiveY2O3is3.5%(molefraction),thegrowthofZrO2grainsisefficientlyinhibited,whichhelpstheZrO2grainsexistinametastabletetragonalmanner;thushigherstrengthandtoughnessareacquired.Whenthecontentofaluminais20%(massfraction),thebendingstrengthandfracturetoughnessofthecompositesare676.7MPaand10MPa·m1/2respectively,themechanicalbehaviorsareclosetothosepreparedwithZrO2andAl2O3powderssynthesizedthroughwetchemicalapproach.Themechanicalbehaviorsofthecompositesarewellimprovedowingtothedispersiontougheningofaluminagrainsandphasetransformationtougheningofzirconiagrains.

简介：Reactionof(MeC5H4)3LnwithHOCH2CH2NMe2intetrahydrofuran(THF)givesthenewcomplexes[(MeC5H4)2Ln(μ-OCH2CH2NMe2)]2(Ln=Sm,Y,Nd)withnitrogenfunctionalizedμ-alkoxideligand.ThecomplexeswerecharacterizedbyelementalanalysisandIR,and[(MeC5H4)2Sm(μ-OCH2CH2NMe2)]2wasstructurallycharacterizedbytheX-raydiffractiontobeadimerformedbytwounsymmetricoxygenbridges.ThecomplexhasatricyclicskeletonwiththeadditionaltwoSm-NbondsviaintramolecularcoordinationofOCH2CH2NMe2.ThecoordinationnumberofthecentralmetalSmisnine.Thetitlecomplexesshowgoodcatalyticactivityforring-openingpolymerizationofε-caprolactone.

简介：结合7m顶装焦炉的工艺和控制要求,介绍7m顶装焦炉设备电气控制系统的构成、功能和特点等。7m顶装焦炉成套设备是太原重工自主研发设计制造的大型炼焦设备,有焦炉车辆联锁系统、焦炉车辆自动对位系统以及带位置检测和记忆功能的炉门装置,其焦炉控制系统控制精度比6m焦炉有了很大提高,达到国内先进水平。

简介：增加的CeO2(ZrO2)/TiO2催化剂独立由大音阶的第五音胶化和受精的方法准备了的一系列镨为选择催化减小被测试没有，并且由X光检查衍射(XRD)描绘了，N2-brumauer-emmett-teller(N2-BET),NH3-temperature规划了解吸附作用(NH3-TPD),H2-temperature规划了减小(H2-TPR),PL系列，拉曼系列，电子顺磁的回声(EPR)一催化性能上的准备方法的影响被学习。结果证明CeO2(ZrO2)/TiO2催化剂的催化性能上的Pr增加的影响在大音阶的第五音胶化方法和受精方法之间是不同的。Pr增加趋于与TiO2交往并且当它是更可能的与在受精方法形成Ce-O-Pr的结构的CeO2交往时，在大音阶的第五音胶化方法形成了Ti-O-Pr的结构。大音阶的第五音胶化方法准备的催化剂的全部的酸数量和氧化还原作用性质与Pr元素的增加减少了，它导致了催化活动的减少。相反，受精方法准备的增加Pr的催化剂被发现拥有更容易的reducibility，更多的全部的酸数量和Ce3+种类的更高的比例，它为更高催化的活动是赞成的。

简介：在甲烷(POM)的部分氧化的催化活动和稳定性混合方法的CeO2-ZrO2和-Al2O3的影响在Ni/Ce0.7Zr0.3O2-Al2O3催化剂上被调查。催化剂被XRD，TPR，H2-chemsorption，和TG-DTA描绘。为新鲜催化剂，结果证明混合催化剂(原子)的盐先锋比混合方法(摩尔)和机械地混合方法(MECH)的粉末的催促的人准备的催化剂介绍了更好的性能。XRD的结果建议在在原子样品的CeO2-ZrO2和Al2O3之间的相互作用比其它强壮，它导致了更多的格子缺点和从而更好的起始的活动。而且，MECH样品在24h稳定性测试有最好的稳定性和最少的焦炭免职。TPR和H2-chemsorption的结果显示在MECH样品的Ni-Al的亲密接触提高了抵抗焦炭免职和金属sintering的能力。

简介：Inthispaper,varioustechniquesincludingBET,XRD,SEMandXPSwereusedtostudythesinteringofpureandLa2O3-dopedtitania.Theexperimentalresultsshowthatsinteringoftitaniaproceedsviavolumediffu-sion.Addingoflanthanumoxidedecreasestherateofsinteringandhindersthephasetransitionfromanatasetorutilecrystalbystrongsurfaceinteractionbetweenthemixedcrystals(La4Ti9O24,La0.66TiO2.99)andTiO2.