简介:合成了氰根桥联配合物Co[Fe(CN)5NO].5H2O,使用元素分析、热重分析、红外光谱、XRD对配合物进行了表征。红外光谱显示金属离子通过氰根桥联即FeII-CN-NiII传递磁相互作用,是属于桥式氰根配体的CN伸缩振动,而粉末XRD衍射图表明此化合物为面心立方体结构(FCC),空间群为Fm3m(225),晶格常数a=10.2856。通过对该配合物的直流变温磁化率和交流磁化率测定表明金属离子通过氰根传递弱反铁磁作用,根据Curie-Weiss定律,拟合数据获得居里常数C=1.55cm3·K/mol,顺磁居里温度θ=-1.87K。
简介:Thestructuralproperties,mechanicalbehavior,andelectronicstructureofthenewlydevelopeddiamondlikeBC5(d-BC5)wasinvestigatedusingdensityfunctionaltheory(DFT)calculations.Theresultsindicatethatd-BC5hasgreatbulkmodulusof393GPa,largeshearmodulusof398GPa,andhighhardnessof62Pa,andthussupportthefactthatd-BC5isanultra-incompressibleandsuperhardmaterial.Remarkably,thesuperhardd-BC5exhibitsmetallicfeatures.Furthermore,thetrendthatthemechanicalbehaviorfallswiththeincreaseofboroncontentwasrevealed.Thecombinationofhugestiffness,highhardness,andgoodmetallicitymakesseriesofdiamondlikeBCx(d-BCx)validforwiderapplicationsincomparisonwithpurediamond.
简介:DarkMatterParticleExplorer(DAMPE)isapowerfulspacetelescopeforhighenergycosmicraysdetectionsuchas-ray,electronandheavyions.ThemainmotivationofDAMPEistofindtheevidenceofdarkmatterexistence,andthesatelliteisscheduledforlaunchingbeforetheendof2015.ThePlasticScintillatorDetector(PSD),whichisoneofthekeycomponentsoftheDAMPEsystem,hastwomajorfunctionalities:distinguishphotonsfromchargedparticlesbyanti-coincidenceandmeasurethechargeofheavyions.ThePSDisdesignedandfabricatedbytheinstituteofmodernphysics,CAS.Itconsistsof82plasticscintillatorstrips,eachofwhichisreadoutbyPMTatbothends,andadouble-dynodereadoutschemeforPMTisutilizedinordertocoverthelargedynamicrange(fromHtoCa).
简介:Asimplemethodisappliedtocalculatingtheisotopeshifts(ISs)on5S1/2→4D3/2,5/2transitionsof87,88Sr+.FirstwehavecalculatedtheISsoflowertransitionsonaseriesofalkali-likesystemssuchasB2+,Ca+andBa+,whichareinagreementwithotherworks.ThentheISson5S1/2→4D3/2,5/2transitionsof87,88Sr+,whichareusefultostudytheSr+opticalfrequencystandard,areevaluated.
简介:Vanadiumalloys(V-Cr-Tiseries)areimportantcandidatematerialsforblanketcomponentsoffusionreactorsduetotheirlowactivationandhighstrengthatelevatedtemperatures.Low-temperatureirradiationembrittlementdeterminestheoperationtemperaturelimitofVanadiumalloysfortheapplicationtostructuralmaterialsoffusionreactorsirradiationresponseofvanadiumalloysneedstobeclarifiedfortheirapplication.Inthepresentstudy,specimensoftwoalloys(V-4Cr-4TiandV-5Cr-5Ti)wereirradiatedwithenergeticHeionsandheavyionstounderstandhardeningofthealloysduetoheliumaccumulationandcascadedamageproduction.
简介:ThemagneticpropertiesofCeRhln5arestudiedbyfirst-principlescalculation.Spin-orbitcouplingisconsideredaswellasdifferentcorrectionsincludinglocaldensityapproximationpluson-siteCoulombinteractionU(U=1,1.5,3eV)andorbitalpolarization.TheresultsshowtheexistenceofonlymoderatecorrelationinCeRhln5andCe-4felectronsareontheborderoflocalizationanditinerancy.Theeffectofpressurebychangingthevolumeoftheunitcellisalsostudied.
简介:在n+~(10)B反应,~5He簇排放与更新的水平计划和新光模型被讨论了参数。在这篇论文,与~5He排放有关的反应隧道详细被列出。由为轻原子核使用新反应模型,为n+~(10)的全部的出去的中子的thedouble微分的生气的节在E_n=14.2兆电子伏的B反应被计算了,并且结果与大小相当同意很好。特别地,在精力尖的系列,对全部的出去的中子双differential十字节的从~5He排放的贡献也被分析了,并且在14.2兆电子伏被给了的E_n=的60°的partialenergy尖的系列。一旦~5He排放被考虑,计算结果显示那,有在低精力区域的全部的出去的中子的double-differentialmeasurements的试穿能被改进。因此,在轻原子核的反应过程适当地认为~是5He排放是必要的。
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简介:AseriesofZSM-5zeolites,withthemorphologiesofsphere,spherewithcubicparticlesonthesurface,andcubicparticles,weresynthesizedbyhydrothermalmethodusingn-butylamineasthetemplate,assistedbytheadditionofNaClandcrystalseed.X-raydiffraction(XRD),scanningelectronmicroscope(SEM),X-rayfluorescence(XRF)andtemperature-programmeddesorptionofammonia(NH3-TPD)wereusedtocharacterizethesesamples.Thesamplesweretestedwithtoluenemethylationreaction.Themodifiedsamplecomposedofsphericalparticleswith3μmcrystalparticlesonthesurfacehadapara-xyleneselectivityof95%andmaintained79%oftheinitialconversionafterrunningthereactionfor50h.Thismodifiedsampleshowedthebeststabilityamongthetestedthreemodifiedsamples.
简介:TheexternalsurfaceofHZSM-5zeolitewaspassivatedbyliquidsiliceousdepositionandbyacidicsitespoisoningwithlepidine,respectively.Thenmethanol-to-hydrocarbons(MTH)reactionwasinvestigatedovertheaboveas-preparedcatalystsandthedissolublecokeontheseusedcatalystswasanalyzedbyGC-MS,tostudytheroleoftheexternalsurfaceofHZSM-5inthecatalyticreaction.ComparisonwiththeexperimentalresultsbasedonparentZSM-5showedthattheproductdistributionofMTHreactionwasobviouslyinfluencedbytheexternalsurface.Evidenceswerelistedasfollows:(1)thefinalproductonparentHZSM-5showedhigheraromaticselectivity,lowerolefinselectivity,lowerratioofC2/C3+aliphaticsandhigherratioofC3/C4+aliphaticsthanthereactionmixtureproducedbythesolecatalysisofacidicsitesinHZSM-5channel;(2)alittleofpentamethylbenzeneandhexamethylbenzeneintheproductonparentHZSM-5,wasproducedviamulti-methylationofmethylbenzeneontheexternalsurface.TheaboveconclusionmayalsobesuitableforMTHreactionoverotherzeoliteswith10-ringchannel.