简介:WeinvestigatereactivefluorineatomspectroscopiccharacterizationinatmosphericpressureofHe/SF6plasmausingatomicemissionspectrometry.Asinputradiofrequency(RF)powerlevelsareraisedfrom140to220W,theemissionspectraof685.60(3p4D→3s4Ptransition)and739.87nm(3p4P→3s4Ptransition)increasesignificantly.Moreover,anoptimalvalueofSF6volumeconcentrationintheproductionoffluorineradicals,whichis0.8%isachieved.AdditionofcertainamountsofO2intoHe/SF6plasmaresultsinthepromotionofSF6dissociation.EmissionintensitiesoffluorineatomsshowthemaximumattheO2/SF6ratioof0.4.
简介:AhighlyTm-dopedleadgermanateglassfiberisdevelopedusingtherod-in-tubemethod.The~2μmlaserbeamqualityofthefiberis~1.5.Theleadgermanatecompositefiberjumpersarehomemadeforallthefiberlaserinvestigations.Whencoreispumpedbya1590nmYb/Erfiberlaser,amaximumlaseroutputof313mWisachievedata670mWpumppower,andthecorrespondingslopeefficiencyis~52.8%.Moreover,byusinga2cmlongleadgermanatefiberasthegainmedium,a33mW1942nmTmlaserisalsodemonstrated.
简介:WereportamonolithicTm:YLFmicrolaserinthisLetter.Inordertoimprovetherelaxationoscillationofthelaser,bothendsofthecrystalarecoated,makingtheTm:YLFcrystalitselfaresonantcavity.Themicrolaserispumpedbya792nmlaserdiodeoperatedinthecontinuouswave(CW)mode.Weobtainmaximumoutputpowersof7.78and10.4Watthetotalincidentpowerof43.6Wwithfocuslensesof37.5and40mm,respectively,correspondingtotheslopeefficienciesof25.6%and40.0%andtheoptical–opticalconversionefficienciesof17.8%and23.8%.Itisclearthattheamplitudeoftherelaxationoscillationissmallerandthebeamqualityisbetterwiththefocuslengthof37.5mm;however,thelaserwiththefocuslengthof40mmproducesahigheroutputpowerandamorestablewavelengthcenteringat1878.44nm.
简介:Aliquid-nitrogen-cooledTm,Ho:YLFlaserisconstructedwitha10-mm-longTm(6%)andHo(0.5%)co-dopedyttriumlithiumfluoridecrystalpumpedbyalaserdiodeoperatingat792nm.ThelaseroutputpowerisimprovedbycoolingtheTm,Ho:YLFcrystalfrom300to77K.Whenthecrystaliskeptat77K,thelaserthresholdpumppoweris230mW,theslopeefficiencyis27.4%,andthemaximumoptical-to-opticalefficiencyis19.9%.Atthesametime,therelationbetweentheinputpowerandtheoutputpoweratdifferenttemperaturesisobtained.
简介:Theeffectofλ/2SiO2overcoatonthelaserdamagecharacteristicsofHfO2/SiO2high-reflector(HR)coatingsisinvestigatedwith1-on-1andN-on-1laserdamagetestmethods.Thelaserdamagesurfaceof1-on-1isanalyzedbyastepanalyzer.ThesurfacemorphologiesshowthatlaserdamagemakesthecoatingdamagedareaprotrudentandroughforHRcoatingwithoutλ/2silicaovercoat,butconcaveandsmoothforHRcoatingwithλ/2silicaovercoat.Theresultof10-on-1multi-pulseirradiationonthesamepointofthecoatingshowsthatthereisanenergydensitystageonthedamagecurve.Ifthelaserenergydensityiswithintherangeofthestage,HfO2/SiO2HRcoatingswithλ/2silicaovercoatwillnotbedamagedmorethan2timesformulti-shots,andthesurfacedamagesareveryslightsothatthereisnoimpactonthecoatingperformance.Anotherinterestingresultisthattheenergydensitystageextendsfromthedamagethresholdtothepointofabout3timesofthreshold,whichissimilartotheeffectofthelaserconditiononcoating.
简介:Thenormalspectralemissivityofniobiumstripspecimenismeasuredusinganewpulse-heatingreflectometrictechnique.Thehemisphericalspectralreflectivityofthesurfaceofastriptangenttoanintegratingsphereisdeterminedbyahigh-speedlock-intechnique.Atthesametime,theradiancetem-peratureofthestripismeasuredbythemulti-wavelengthhigh-speedpyrometerfromapproximately1000Ktothemeltingpoint.Detailsofthemeasurementmethodandoftherelatedcalibrationtechniquesarereported.Resultsofthenormalspectralemissivityofniobiumat633,753,827,and905nmfromroomtemperaturetoitsmeltingpointarepresented.Theaccuracyofspectralemissivitiesisestimatedbetterthan5%.
简介:Enhanced2.7μmemissionisobtainedinEr3+/Tm3+andEr3+/Ho3+codopedZBYAglasses.Absorptionandemissionspectraaretestedtocharacterizethe2.7μmemissionpropertiesofEr3+/Tm3+andEr3+/Ho3+dopedZBYAglassesandareasonableenergytransfermechanismof2.7μmemissionbetweenEr3+andTm3+Ho3+)ionisproposed.CodopingofTm3+orHo3+significantlyreducesthelifetimeoftheEr3+:4I13/2levelduetotheenergytransferofEr3+:4I13/2→Tm3+:3F4orEr3+:4I13/2→Ho3+:5I7.Thus,the2.7μmemissionisstrengthenedandthe1.5μmemissionisdecreasedaccordinglyespeciallyintheEr3+/Tm3+sample.TheupconversioneffectsbetweentheEr3+/Tm3+andEr3+/Ho3+dopedZBYAglassesaredifferentattributetothedifferentenergytransferefficiencies.Bothofthetwocodopedsamplespossessnearlyequallargeemissioncrosssection(16.6×10-21cm-2)around2.7μm.TheresultsindicatethatthisEr3+/Tm3+orEr3+/Ho3+dopedZBYAglasshaspotentialapplicationsin2.7μmlaser.
简介:Thenonlinearswitchingcharacteristicsoffusedfiberdirectionalcouplerswerestudiedexperimentally.Byusingfemtosecondlaserpulseswithpulsewidthof100fsandwavelengthofabout1550nmfromasystemofTi:sapphirelaserandopticalparametricamplifier(OPA),thenonlinearswitchingpropertiesofanullcoupleranda100%couplerweremeasured.Theexperimentalresultswerecoincidentwiththesimulationsbasedonnonlinearpropagationequationsinfiberbyusingsuper-modetheory.Nonlinearlossinfiberwasalsomeasuredtogettheinjectedpoweratthecoupler.Afterdeductingthenonlinearlossandinputefficiency,thenonlinearswitchingcriticalpeakpowersfora100%andanullfusedcouplerswerecalculatedtobe9410and9440W,respectively.ThenonlinearlossparameterPNinanexpressionofαNL=αP/PNwasobtainedtobePN=0.23W.
简介:Wedemonstrateadiode-pumpTm3+t-dopedall-fiberlaseroperatingat1908nmbasedonamasteroscillatorpoweramplifier(MOPA)configuration.Inourwork,152Woflaseroutputpowerisgeneratedbyatotalincidentpumppowerof434Wat790nm,correspondingtothetotalopticalefficiencyof35%.Thelaserwavelengthis1908.29nm.Tothebestofourknowledge,itisthehighestoutputpowerreachedaround1908nmwithsuchanarrowlinewidthof0.18nmbasedonaMOPAconfiguration.
简介:Thepotentialenergycurves(PECs)ofBOmolecule,includingΣ+andΠsymmetrieswithdoubletspinmultiplicities,areobtainedemployingmulti-referenceconfigurationinteraction(MRCI)methodandDunning'scorrelationconsistentbasissets.Theanalyticalpotentialenergyfunctions(APEFs)arefittedusingtheMurrell-Sorbie(MS)functionandtheleastsquaremethod.BasedonthePECs,thespectroscopicconstantsofthestateshavebeendeterminedandcomparedwiththetheoreticalandexperimentalresultsavailabletoaffirmtheaccuracyandliabilityofthecalculations.Theroot-mean-square(RMS)errorsbetweenthefittedresultsandtheabinitiovaluesaretoolittleincomparisonwiththechemicalaccuracy(349.755cm-1).ItisshownthatthepresentAPEFsareaccurateandcandisplaytheinteractionbetweentheatomswell.ThepresentAPEFscanbeusedtoconstructmorecomplicatedAPEFordosomedynamicinvestigations.
简介:Usingamicrowavegenerator,chlorinedilutedbyheliumwasdissociatedtochlorineatomsthatsubse-quentlyreactedwithhydrogenazidetoproducetheexcitedstatesofNCl(a1△).Meanwhile,moleculariodinewithcarriergasofheliumreactedwithatomicchlorinetoproduceatomiciodinewhichthenwaspumpedtoexcitedstateofI(2P1/2)byanenergytransferreactionfromNCl(a1△).Inthispaper,thechangesofNCl(a1△)andNCl(bi∑)emissionintensityispresentedwhenI2/HeisintroducedintothestreamofCl/Cl2/He/HN3/NCl(a1△)/NCl(b1∑).ThedependencesofatomiciodineI(2P1/2)onflowratesofgaseswerealsoinvestigated.TheoptimumparametersforI(2P1/2)productionaregiven.
简介:FourkindsofY2O3stabilizedZrO2(YSZ)thinfilmswithdifferentY2O3contents(from0to12mol%)aredepositedonBK7glasssubstratesbyelectron-beamevaporationmethod.TheeffectsofdifferentY2O3dopantcontentsonresidualstress,structure,andopticalpropertiesofZrO2thinfilmsareinvestigated.TheresultsshowthatresidualstressinYSZthinfilmsvariesfromtensiletocompressivewiththeincreaseofY2O3molarcontent.TheadditionofY2O3isbeneficialtothecrystallizationofYSZthinfilmandtransformationfromamorphoustohightemperaturephase,andtherefractiveindexdecreaseswiththeincreaseofY2O3molarcontent.Moreover,thevariationsofresidualstressandtheshiftsofrefractiveindexcorrespondtotheevolutionofstructuresinducedbytheadditionofY2O3.
简介:Ag-MgF2cermetfilmswithdifferentAgfractionswerepreparedbyvacuumevaporation.Themicrostruc-tureofthefilmswasexaminedbyRamanscatteringtechnique.Thesurface-enhancedRamanspectrumforMgF2moleculesinthecermetfilmstronglysuggeststheexistenceofAgnanoparticlesdispersedinMgF2matrix.TheintensitiesoftheRamanspectraofAg-MgF2cermetfilmsincreasewithAgfraction.TheenhancementofRamanscatteringdisappearswhenAgcontentreacheswt.20%.TheanalyseswiththetransmissionelectronmicroscopyshowedthatAg-MgF2cermetfilmsaremainlycomposedofamor-phousMgF2matrixwithembeddedfaced-center-cubicAgnanoparticles.Itsuggeststhatthepercolationthresholdshouldbearoundwt.20%ofAgcontent.
简介:Nitridatedβ-Ga_2O_3(100)substratewasinvestigatedasthesubstrateforGaNepitaxialgrowth.Theeffectsofnitridationtemperatureandsurfaceroughnessofβ-Ga_2O_3wafersontheformationofGaNwerestudied.Itwasfoundthatthemostoptimizednitridationtemperaturewas900°C,andhexagonalGaNwithpreferredorientationwasproducedonthewell-polishedwafer.Thenitridationmechanismwasalsodiscussed.
简介:AprototypeRamanlidarwasdesignedformonitoringtroposphericCO_2profileandotherscientificin-vestigations.ThethirdharmonicofNd:YAGlaser(354.7-nmwavelength)wasusedasstimulatedlightsourcetoprovidenighttimemeasurements.FilterwithhighrejectionratioperformancewasusedtoextractCO_2RamansignalsfromRayleigh-Miescatteringsignalseffectively.Toimprovetherealtimemonitoringfunction,atwo-channelsignalcollectionsystemwasdesignedtocollectCO_2andN_2Ramanscatteringsig-nalssimultaneously.TheN_2Ramanscatteringsignalswereusedtoretrieveaerosolextinctioncoefficient.TypicalfeaturesofCO_2concentrationprofileandaerosolextinctioncoefficientinHefeiwerepresented.ThemixingratioofatmosphericCO_2inHefeicanreachabout360-400ppmv.
简介:Wereportthefabricationofsubmicrometerpitsarray(SP-array)on6H-SiCsurfacebytheinterferenceoftwofemtosecondlaserbeams.FormationmechanismsandopticalabsorptionofSP-arrayarestudied.Therelativereflectivityandtransmissivityofwhitelightdecreaseto10%ofthevaluesofSiCcrystal,andtheopticalabsorptionisenhancedto97%.Therelativereflectivityandtransmissivityofincidentangleswithintherangeof20°-60°arekeptbelow25%.TheenhancementmechanismofopticalabsorptionoftheSP-arrayisalsodiscussed.