简介:Analyticalsolutionsfortheelasticpropertiesofavarietyofbinarynanotubeswitharbitrarychiralityareobtainedthroughthestudyofsystematicmolecularmechanics.Thismolecularmechanicsmodelisfirstextendedtochiralbinarynanotubesbyintroducinganadditionaloutof-planeinversiontermintotheso-calledstick-spiralmodel,whichresultsfromthepolarbondsandthebucklingofbinarygraphiticcrystals.Theclosed-formexpressionsforthelongitudinalandcircumferentialYoung’smodulusandPoisson’sratioofchiralbinarynanotubesarederivedasfunctionsofthetubediameter.Theobtainedinversionforceconstantsarenegativeforalltypesofbinarynanotubes,andthepredictedtubestiffnessislowerthanthatbytheformerstick-spiralmodelwithoutconsiderationoftheinversionterm,reflectingthesofteningeffectofthebucklingontheelasticpropertiesofbinarynanotubes.Theobtainedpropertiesareshowntobecomparabletoavailabledensityfunctionaltheorycalculatedresultsandtobechiralityandsizesensitive.ThedevelopedmodelandexplicitsolutionsprovideasystematicunderstandingofthemechanicalperformanceofbinarynanotubesconsistingofIII–VandII–VIgroupelements.
简介:BasedonthemethodofseparatingvariablesandthetechniqueofMuller’scalculatingroots,thepropagationcharacteristicsofhybridmodesinhomogeneousandinhomogeneouscircularFaradaychirowaveguidesareexaminedindetail.Numericalresultsarepresentedtodemonstratethecombinedeffectsofdifferentconstitutiveparametersonthemodebifurcation,symmetryandnonreciprocity,backward-waveandattenuationofhybridmodes,whicharedifferentfromthecasesofordinarygyrotropicandreciprocalchiralwaveguides.
简介:Thecrystalstructureoftetrakis[(pyrrol-1-yl)methyl]methanewasdeterminedbyX-raydiffractionmeasurement,andtheresultshowsthatitbelongstomonocliniccrystalsystem,spacegroupisP21/n,witha=0.9284(3)nm,b=1.0950(6)nm,c=1.8749(8)nm;α=γ=90.00(4)°,β=103.63(3)°,V=1.8523(14)nm3,Z=4,ρcalcd.=1.192kg/m3,μ=0.072nm-1,F(000)=712,R1=0.0854,wR2=0.1884.Ithasbeenfoundthatthemoleculesexistintwoenantiomericstates.Enantioselectiveself-assembliessuchasone-dimensionalmolecularstacksinasinglehandedness,homochiralmonolayersandachiralsuperlatticearespecifiedinthisracemiccrystal.Inaddition,asimpletechniqueisadvocatedtodistinguishchiralstatesfromtetrahedralmoleculesinthesolidstate.ThepresentR/Snomenclatureofthetetracooradinatedcarboncentersisusedsolelyforitsconveniencetodistinguishthetwoenantiomericstates,butnotusedtodeterminetheabsoluteconfigurations.