简介:Anenvironmentallyfriendlyprecursor,adenosine,hasbeenusedasadualsourceofCandNtosynthesizenitrogen-dopedcarboncatalystwith/withoutFe.Ahydrothermalcarbonizationmethodhasbeenusedandwateristhecarbonizationmedia.Themorphologyofsampleswith/withoutFecomponenthasbeencomparedbyHRTEM,andtheresultshowsthatFecanpromotethegraphitizationofcarbon.Furtherelectro-chemicaltestshowsthattheoxygenreductionreaction(ORR)catalyticactivityofFe-containingsample(C–FeN)ismuchhigherthanthatoftheFe-freesample(C–N).Additionally,theintermediatesofC–FeNformedduringeachsyntheticprocedurehavebeenthoroughlycharacterizedbymultiplemethods,andthefunctionofeachprocedurehasbeendiscussed.TheC–FeNsampleexhibitshighelectro-catalyticstabilityandsuperiorelectro-catalyticactivitytowardORRinalkalinemedia,withitshalf-wavepotential20mVlowerthanthatofcommercialPt/C(40wt%).Itisfurtherincorporatedintoalkalinepolymerelectrolytefuelcell(APEFC)asthecathodematerialandledtoapowerdensityof100mW/cm~2.
简介:Weintroducethenotionofproperty(RD)foralocallycompact,Hausdorffandr-discretegroupoidG,andshowthatthesetS2^l(G)ofrapidlydecreasingfunctionsonGwithrespecttoacontinuouslengthfunctionIisadensespectralinvariantandFreehet*-subalgebraofthereducedgroupoidC^*-algebraCr^*.(G)ofGwhenGhasproperty(RD)withrespecttol,sotheK-theoriesofbothalgebrasareisomorphicunderinclusion.EachnormalizedcoeycleconG,togetherwithaninvariantprobabilitymeasureontheunitspaceGoofG,givesrisetoacanonicalmapTconthealgebraCo(G)ofcomplexcontinuousfunctionswithcompactsupportonG.WeshowthatthemapTccanbeextendedcontinuouslytoS2^l(G)andplaysthesameroleasann-traceonCr^*(G)whenGhasproperty(RD)andcisofpolynomialgrowthwithrespecttol,sotheConnes'fundamentparingbetweentheK-theoryandthecycliccohomologygivesustheK-theoryinvariantsonCr^*(G).
简介:Letp(z)=a_0+a_1z+a_2z~2+a_3z~3+···+a_nz~nbeapolynomialofdegreen.Rivlin[12]provedthatifp(z)≠0intheunitdisk,thenfor0
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简介:Amodelstudyleadingtothepreparationoftheuniquetricyclo[6.2.1.0]undecaneBCDringsystemsofaconitineisdescribed.Thesynthesisfeaturesanunprecedenteddiastereoselectiveoxidativedearomatization/dimerization/retro-DA/IMDAcascadereactionandahighlyefficientWagner-Meerweinrearrangement.
简介:Two-dimensional(2D)graphitecarbonnitride(g-C3N4)nanosheetshavebeensuccessfullyusedasasaturableabsorber(SA)inapassivelyQ-switchedNd:LLFlaserat1.3μmforthefirsttime,tothebestofourknowledge.Underanincidentpumppowerof9.97W,theshortestpulsedurationof275nswasacquiredwithoutputpowerof0.96Wandpulserepetitionrateof154kHz,resultinginapulseenergyof6.2μJ.Inaddition,thesaturableabsorptionbehaviorsofzero-dimensional12nmg-C3N4nanoparticles(g-C3N4-NPs)andthree-dimensionalorderedmesoporousg-C3N4(mpg-C3N4)werealsoobserved,althoughtheirmorphologyandstructurewerequitedifferentfrom2Dg-C3N4.Theexperimentalresultsintroducethepotentialapplicationofg-C3N4nanomaterialsasSAsinQ-switchedlasers.
简介:为了解决M/M/c模型在实际运用中模拟精度不高及使用范围有限的问题,本文立足系统状态变化与输入率和服务率的关系,通过引入输入概率和服务度,构建依赖系统状态的递进式输入率和服务率。递进式输入率和服务率通过研究系统实际运行状况设定临界值,其中输入率分为两阶段,服务率分为三阶段。此外,结合递进式输入率和服务率及排队论状态转移过程构建了递进式M/M/c模型,并采用后确定法确定模型参数。递进式M/M/c模型是M/M/c模型的扩展形式,提高了M/M/e模型的模拟精度,在一定程度上拓展了模型的应用范围。最后,通过一个生活实例验证了递进式M/M/c模型的优化性和实用性。
简介:DirectC—HfunctionalizationofquinolineN-oxideswitharylboronicacidsisachievedusingKMnO_4asthesoleandefficientoxidativesystem.Thismethodprovidesanefficientprotocoltoconstructregioselectively2-arylquinolineN-oxidesviaradicalcross-couplingreactioninmoderatedtogoodyieldsundermildconditions.
简介:Theneworganic-inorganiccompound,[C_6H_7N_2O_2]_3TeCl_5·2Clwassynthesizedanditsstructurewasdeterminedatroomtemperatureinthetriclinicsystem(P~-1)withthefollowingparameters:a=10.5330(11)?,b=10.6663(11)?,c=15.9751(16)?,α=82.090(2)°,β=71.193(2)°,γ=68.284(2)°andZ=2.ThefinalcycleofrefinementledtoR=0.057andRw=0.149.ThecrystalstructurewasstabilizedbyanextensivenetworkofN--H···Clandnon-classicalC--H···Clhydrogenbondsbetweenthecationandtheanionicgroup.Severalthermalanalysistechniquessuchasthermogravimetricanalysis,differentialscanningcalorimetricanalysisandevolvedgasanalysiswereused.Weusedisoconversionalkineticsmethodstodeterminethekineticsparameters.Weobservethatthedecompositionof[C_6H_7N_2O_2]_3TeCl_5·2Clentailstheformationhydrochloricacidofnitroanilineasvolatiles.Theinfraredspectrawererecordedinthe4000–400cm~(-1)frequencyregion.TheRamanspectrawererecordedintheexternalregionoftheanionicsublatticevibration50–1500cm~(-1).TheopticalbandgapwascalculatedfromtheUV-VisabsorbancespectrausingclassicalTaucrelationwhichwasfoundtobe3.12and3.67eV.