学科分类
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69 个结果
  • 简介:底层的wettability和粗糙在无柄的微滴的蒸发对接触角度和三阶段的接触线的进化关键。在这份报纸,由在nanoscale为微滴蒸发执行分子的动力学模拟,我们证明wettability比粗糙更重要。为光滑的底层,nanodroplet的蒸发行为在宏观的规模类似于那。这类似也在不平的吸水的底层的情况中被观察。为不平的恐水病的底层,然而,卡住的经常的接触角度和接触线在蒸发期间接着出现。这建议恐水病的底层的粗糙为蒸发技术在是有用的在nanoscale自己组装。

  • 标签: 蒸发过程 粗糙度 基底 纳米尺度 动力学模拟 液滴蒸发
  • 简介:Amethodhasbeendevisedtoanalyzemultilayerelectricallythickcircularmi-crostripantennaexcitedbyaprobe.Thecurrentontheprobeistakentobeuniform.Thismethodwasverifiedbyanalysisandexperimentofanelectricallythickcircularmicrostripan-tennawithanairgap.BasedonthefreespaceelectricdyadicGreen’sfunction,thefieldexpressionofanhorizontalelectricdipole(HED),whichislocatedatanypointofthemultilayermediaandpointsinanydirection,hasbeenderived.ByusingthisfieldexpressionandtheRichmondre-actionequation,anintegralequationintermsofelectriccurrentonthepatchisformulated.Byproperlychoosingcurrentexpansionmodes,thismethodcanbeusedforanelectricallythickmi-crostripantenna.Thetheoreticalresultsagreeverywellwithexperimentaldataforanelectricallythickcircularmicrostripantennawithanairgap.

  • 标签: ANTENNA MICROWAVE ANTENNA MULTILAYER SUBSTRATE
  • 简介:ThepurecubicGaN(c-GaN)hasbeengrownon(001)GaAssubstratesbyECR-PAMOCVDtechniqueatlowtemperatureusingTMGaandhighpureN2asGaandNsources,respectively.TheeffectsofsubstratepretreatmentconditionsonqualityofcubicGaNepilayerareinvestigatedbythemeasurementsofTEMandXRD.Itisfoundthathydrogenplasmacleaning,nitridationandbufferlayergrowthareveryimportantforqualityofcubicGaNepilayer.

  • 标签: 氮化镓 立方体 氢等离子体 渗氮 缓冲层
  • 简介:Moleculardynamics(MD)simulationsareperformedtostudyadhesionandpeelingofashortfragmentofsinglestrandDNA(ssDNA)moleculefromagraphitesurface.Thecriticalpeel-offforceisfoundtodependonboththepeelingangleandtheelasticityofssDNA.FortheshortssDNAstrandunderinvestigation,weshowthatthesimulationresultscanbeexplainedbyacontinuummodelofanadhesiveelasticbandonsubstrate.Theanalysissuggeststhatitisoftenthepeakvalue,ratherthanthemeanvalue,ofadhesionenergywhichdeterminesthepeelingofananoscalematerial.

  • 标签: 分子动态模拟 DNA 培养基 表面支持 弹性模型
  • 简介:TheheterogeneousnucleationbehaviorsofNH4ClcrystalonroughaluminumsubstratesurfaceimmergedinNH4Cl-H2Osolutionwereexperimentallyanalyzed,andtheinfluencemechanismofthemicro/nano-scalesurfacestructuresonheterogeneousnucleationwasinvestigated.Ithasbeenshownthatwettabilityandnucleationareaffectedbysubstratesurfacecondition.Theintrinsicwettingpropertiesbetweennucleusandsubstratesurface,andthesurfacestructureofcertaingeometricalscales,bothimposeeffectsontheheterogeneousnucleationproperties.Foranucleus-wettingsubstratesurface,heterogeneousnucleationispromotedbyahighercomplexityofthesurfacemorphology;butforanucleus-nonwettingsubstratesurface,heterogeneousnucleationisinhibitedbyahighercomplexityofthesurfacemorphology.

  • 标签: 表面结构 晶体成核 润湿性 铝基材 异相成核 表面形态
  • 简介:TheheterogeneousnucleationbehaviorsofNH4ClcrystalonaroughchillingsurfaceofaluminumimmergedinNH4Cl-H2Osolutionwereexperimentallyanalyzedandtherelationshipbetweenthesurfaceroughnessandthenucleationsiteselectionbehaviorsonpolishedaluminumsubstratewasinvestigated,anditwasdiscoveredthatthenumberofnucleationsitesdecreasessignificantlywithdecreasingtheroughnessofthepolishedsubstrate.Furthernucleationexperimentswerecarriedoutonchemicallyetchedaluminumsubstratewithregularmicro-morphologyonitssurface.Ithasbeenshownthatboththemicro-morphologyandthewettabilityvarywiththesubstratesurfacepreparedbydifferentetchingprocess.Thepreparedsurfacewithstep-likestructureshasastrongwettabilitywithNH4Cl-70wt%H2OsolutionandthenucleationdensityofNH4Clontheitssurfacesissignificantlyhigherthanthatofthereferencesurfaces,whichshowsthatthegeometricalmorphologyfeatureshaveimportanteffectsonboththewettabilityandthenucleationbehaviors.

  • 标签: 英文摘要 材料科学 优秀论文 科技学报
  • 简介:Electronicsystemswithlargestretchabilityhavemanyapplications.Apreciselycontrolledbucklingstrategytoincreasethestretchabilityhasbeendemonstratedbycombininglithographicallypatternedsurfacebondingchemistryandabucklingprocess.Thebuckledgeometrywasassumedtohaveasinusoidalform,whichmayresultinerrorstodeterminethestrainsinthefilm.Atheoreticalmodelispresentedinthislettertostudythemechanicsofthistypeofthinfilm/substratesystembydiscardingtheass...

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  • 简介:最近的数字模拟显示了在cellsubstrate粘附期间聚类的integrin能被在房间膜和底层之间的排斥的层的存在驾驶(Paszek等,PLoSComputBiol5:12,2009)。这里我们在场在integrins之间的吸引力被膜和排斥的层的远程的有弹性的变丑在调停的这现象的一个简单力学模型。我们由采用在一个有弹性的基础上休息的一个无穷地扩大的盘子的小变丑理论获得分析答案到这个问题。

  • 标签: 力学模型 整合素 附着力 基材 聚集 数值模拟
  • 简介:构造沼泽地(CW)是包括沼泽地植被,土壤,和他们在对待废水帮助的联系微生物引起的集合利用自然系统的设计系统。由象强风炉子炉渣(BFS)那样的CW底层材料的铵氮(NH+4-N)的运动吸附,沸石,ceramsite,蛭石,石子,稻土壤,红土壤,和草地,用批实验和运动吸附等温线被调查。Freundlich和Lang-muir等温线能足够地预言NH+4-N吸附过程。NH+4-N的最大的吸附能力,从兰米尔等温线估计了,是评价:沸石(33333.33mgkg1)>草地(29274.01mgkg1)>BFS(5000mgkg1)>蛭石(3333.33mgkg1)>石子(769.23mgkg1)>稻土壤(588.24mgkg1)>红土壤(555.56mgkg1)>ceramsite(107.53mgkg1)。底层材料的一些性质包括体积密度,比重,水力的电导率,一致性系数(K60),弯曲系数(Cc),有机物,pH,可交换(或活跃)Cu,Fe,Zn和Mn,全部的Cu,和Fe,Mn,Zn,Cd,Pb和Ca,与NH+4-N的有的否定关联吸附。底层材料的另外的性质喜欢D10,D30和D60(分别地,10%,30%和60%基于积聚的频率粒子在通过筛的底层材料的粒子尺寸的直径)的粒子直径价值,阳离子交换能力(CEC),可交换(或活跃)Ca和Mg,和全部的K和Mg与NH+4-N有积极关联吸附。另外,象全部的Na一样的活跃K和Na与NH+4-N吸附有重要积极关联。这个信息将为为CW的合适的底层材料的选择是有用的。

  • 标签: 吸附动力学 人工湿地 铵态氮 基体材料 LANGMUIR 吸附等温线
  • 简介:Tostudythemechanicalpropertiesofthefilm/substratestructure,thefiniteelementcodeABAQUSv6.9-1isadoptedtosimulatethetensilemechanicalbehaviorofthenanoscalethinfilmbondedtoasubstrate.Thebifurcationphenomenonofthestructureunderuniaxialtensionisfound:thesingle-neckdeformation,themultiple-neckdeformationandtheuniformdeformation.Thesubstrateandthefilmareregardedaspower-hardeningmaterialsobeyingtheJ2deformationtheory.Firstly,theinfluenceofmaterialhardeningmatchontensilebifurcationmodeisanalyzedunderperfectlywell-bondedinterfacecondition.Then,theeffectsofinterfacialstiffnessandothersuperficialdefectssurroundingtheimperfectiononbifurcationmodeareinvestigated.Itisconcludedthatunderthewell-bondedinterfacecondition,ifthestressofthesubstrateislargerthanthefilm,thefilmwilluniformlydeformwiththesubstrate;ifthestressofthesubstrateissmallerthanthefilm,thefilmwillformasingleneck,exceptthecasethataweakly-hardeningfilmisbondedtoasteeply-hardeningsubstratewhenmultipleneckscanbeformed.Withthedecreaseofinterfacialstiffness,theuniformdeformationmodecantransformintothemultiple-neckdeformationmode,andfurthertransformintothesingle-neckdeformationmode.Andotherdefectssurroundingtheimperfectioncaninfluencethewavelengthofdeformationandnecknumber.

  • 标签: 单轴拉伸 分叉现象 基板 电影 数值分析 均匀变形
  • 简介:Themicro-characteristicsofthestreakymarksandthecorrespondingsubstratesurfaceofgalvannealed(GA)steelsheetshavebeeninvestigatedusingSEMandFIB.Thestreakymarkareaseemstohavemanycavities,similartocraters,whichscatterlightandmakethesurfaceappeardarkerwhencomparedwiththesurroundingnormalarea.Moreover,itisfoundthattheirregularityordifferenceinsteelgrainsizetendstoaffectthesurfacequalityoftheGAsteelsheets.Duringalloying,thediffusionspeedofZn-Feonthegrainboundaryisfasterthanthatatthecenterofthegrain,whichresultsintheselectiveformationofcrater-likemorphologyinthecoatingareawithlargersteelgrains.DuetothecleargrainboundaryofIFsteel,apparentstreakymarkswillbeformedonthecoatin,iftheIFsteelsurfaceconsistsofrainsofirreularsize.

  • 标签: 晶粒尺寸效应 遗传标记 IF钢 基板 合金化热镀锌 表面质量
  • 简介:Thinfilm/substratematerialsystemshavebeenwidelyusedinvariousindustriessuchasaerospace,automotive,marineandelectronics.Oneexampleisthermalbarriercoatings(TBCs):TBCsareextensivelyappliedtometalliccomponentsongasturbineenginesinordertoprotectthemfromhighandprolongedheatloads,andtheyplayanessentialroleintheaircraftindustry.Anotherexampleislaminatedpolymermatrixcomposites(PMCs),reinforcedwithfiberssuchascarbon,glassoraramid:Thesematerialshavebeenextensivelyemployedinavarietyofapplicationsduetotheirsuperiorpropertiesandtheimprovingeaseandcost-effectivenessoffabricatingthem.Theevaluationofmechanicalpropertiesforthinfilm/substratematerialsystemsisimperativeformoreefficientuseofthesematerialsystemsandfurtherimprovements.

  • 标签: TBCS PMCs VARIOUS INDUSTRIES
  • 简介:Thisarticle,bycomparingthebasicconceptsofsubstrateandsoil,theircompositionofsubstanceandmethodsofmeasuringtheindexesofphysicalandchemicalproperties,analyzesandresearcheswaysofchoosingsubstrateforcultivationwithfacilities.Itindicatesthatthenormalphysicalandchemicalindexesofevaluatingasubstratearebulkdensity,totalporosity,non-capillaryporosity,ratioofbigporositytosmallporosity,thepHandtheelectricalconductivity(EC)valueofthesubstrate.By...

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  • 简介:Wehaveinvestigatedthephysicalproperties,includingthemorphology,texture,adhesionandchemicalquality,ofhigh-frequencychemicalvapourdepositeddiamondcoatingsonWC-6%Cosubstrates,whichwerepre-treatedbyatwo-stepetchingmethod.TheresultsindicatethattheincreasingCocontentfrom0.12to3.05%withintheetchingdepthof5μmcausedamorphologytransformationfromprismdiamondtospheruliticdiamond,andatexturetransformationfroma{111}orientationtoa{110}orientation.TheRamanspectrumshowsthatthespheruliticdiamondfilmcontainsmorenon-diamondphases(graphite,amorphouscarbonanddiamond-likecarbon,etc)andhaslowerchemicalqualitythandiamondfilmsonaWC-6%Cosubstrate.Thediamondcoatinggrainsizesbecameaboutfourtimessmallerwhenthedepositiontemperaturesonthesubstratesurfacewerereducedfrom1000to900℃.Comparedwithspheruliticdiamondfilms,theprismdiamondfilmsexhibitbetteradhesionontheWC-6%Cosubstrate.

  • 标签: 金刚石 化学汽相淀积 金刚石薄膜
  • 简介:Geepilayersofdifferentthicknessesaregrownbymolecular-beamepitaxywithSbasasurfactantonSI(100)substrates,X-raydiffractionillustratesthattheseGethinfilmsarepartiallystrained.andthestrainsdecreasegraduallywithincreasingepilayerthickness,RamanspectrarevealadownwardshiftoftheGe-Gemodepeakastheepilayerthicknessincreases.Intheregionsofhighstrain,therelationshipbetweentheRamanshiftofthismodeandthestraininthepartiallyrelaxedsamplesisconsiderablydifferentfromthelinearrelationshipreportedbefore,whichismainlyattributedtothespatialconfinementeffectofphononsinananocrystal.

  • 标签: 镓外延薄膜 硅衬底 形变研究
  • 简介:Thisstudyconcernsatwo-dimensionalmodelandthecorrespondingvirtualcrackclosuretechnique(VCCT)implementedtosolvethegeneralboundaryvalueproblemsthatmayexplainwhyinterfacediscontinuityhaseffectsonthefracturebehaviorinthesuperconductor-substratesystem.Theinterfacialdiscontinuitycanbeclassifiedaccordingtothematerialproperties'continuityandtheirderivatives'continuityattheinterface.Fornonhomogeneoussuperconductorandsubstratespecimenswithvariousmaterialproperties,aVCCTmethodisdevelopedtocalculatetheirfracturebehavior.Furthermore,theeffectsofappliedmagneticfieldamplitudeandnonhomogeneousparametersareextensivelyandparametricallystudiedintwoactivationprocesses(zero-fieldcoolingandfieldcooling).Theintegrativeandcomputationalstudypresentedhereprovideafundamentalmechanisticunderstandingofthefracturemechanisminthesuperconductor-substratesystemandshedslightontherationaldesignofinterfacialcontinuity.

  • 标签: Superconductor-substrate SYSTEM INTERFACIAL DISCONTINUITY Fracture behavior
  • 简介:Tetrahedralamorphoushydrogenatedcarbon(ta-C:H)filmsonSi(lO0)substrateswerepreparedbyusingamagnetic-field-filterplasmastreamdepositionsystem.Sampleswithdifferentratiosofsp^3-bondtosp^2-bondwereobtainedbychangingthebiasvoltageappliedtothesubstrates.Theellipsometricspectraofvariouscarbonfilmsinthephotonenergyrangeof1.9-5.4eVweremeasured.Therefractiveindexnandtherelativesp^3CratioofthesefilmswereobtainedbysimulatingtheirellipsometricspectrausingtheForouhi-BloomermodelandbyusingtheBruggemaneffectivemediumapproximation,respectively.Thehaemocompatibilityoftheseta-C:Hfilmswasanalysedbyobservationofplateletadhesionandmeasurementofkineticclottingtime.Theresultsshowthatthesp^3Cfractionisdependentonthesubstratebiasvoltage,andthehaemocompatibilityisdependentontheratioofsp^3-bondtosp^2-bond.Agoodhaemocompatibilitymaterialofta-C:Hfilmswithasuitablesp^3Cfractioncanbepreparedbychangingthesubstratebiasvoltage.

  • 标签: 逼近性 碳膜 中子衍射 磁场 SEM
  • 简介:Anewmethodforthedeterminationoftracecalciumbysolidsubstrate-roomtemperaturephosphorimetryisestablished.ItisbasedonthefactthatchromeazurolsazurolS-phenanthroline-NaCMC(CAS-phen-NaCMC)systemcanemitstrongandstableroomtemperaturephosphorescence(RTF)onthesolidsubstrateinthefilterpaper.Ca2+andphenanthrolinecanformcomplexionCa(phen)32+,whichwillformcomplex[Ca(phen)3(CAS)2]withCAS.Intheresult,thenumberofCASmoleculesineachspotincreased,causingsharpincreaseoftheRTPsignaloftheCAS-phen-NaCMCsystem.

  • 标签: CALCIUM Solid substrate-room temperature phosphorimetry Sodium