简介:Amethodhasbeendevisedtoanalyzemultilayerelectricallythickcircularmi-crostripantennaexcitedbyaprobe.Thecurrentontheprobeistakentobeuniform.Thismethodwasverifiedbyanalysisandexperimentofanelectricallythickcircularmicrostripan-tennawithanairgap.BasedonthefreespaceelectricdyadicGreen’sfunction,thefieldexpressionofanhorizontalelectricdipole(HED),whichislocatedatanypointofthemultilayermediaandpointsinanydirection,hasbeenderived.ByusingthisfieldexpressionandtheRichmondre-actionequation,anintegralequationintermsofelectriccurrentonthepatchisformulated.Byproperlychoosingcurrentexpansionmodes,thismethodcanbeusedforanelectricallythickmi-crostripantenna.Thetheoreticalresultsagreeverywellwithexperimentaldataforanelectricallythickcircularmicrostripantennawithanairgap.
简介:ThepurecubicGaN(c-GaN)hasbeengrownon(001)GaAssubstratesbyECR-PAMOCVDtechniqueatlowtemperatureusingTMGaandhighpureN2asGaandNsources,respectively.TheeffectsofsubstratepretreatmentconditionsonqualityofcubicGaNepilayerareinvestigatedbythemeasurementsofTEMandXRD.Itisfoundthathydrogenplasmacleaning,nitridationandbufferlayergrowthareveryimportantforqualityofcubicGaNepilayer.
简介:Moleculardynamics(MD)simulationsareperformedtostudyadhesionandpeelingofashortfragmentofsinglestrandDNA(ssDNA)moleculefromagraphitesurface.Thecriticalpeel-offforceisfoundtodependonboththepeelingangleandtheelasticityofssDNA.FortheshortssDNAstrandunderinvestigation,weshowthatthesimulationresultscanbeexplainedbyacontinuummodelofanadhesiveelasticbandonsubstrate.Theanalysissuggeststhatitisoftenthepeakvalue,ratherthanthemeanvalue,ofadhesionenergywhichdeterminesthepeelingofananoscalematerial.
简介:TheheterogeneousnucleationbehaviorsofNH4ClcrystalonroughaluminumsubstratesurfaceimmergedinNH4Cl-H2Osolutionwereexperimentallyanalyzed,andtheinfluencemechanismofthemicro/nano-scalesurfacestructuresonheterogeneousnucleationwasinvestigated.Ithasbeenshownthatwettabilityandnucleationareaffectedbysubstratesurfacecondition.Theintrinsicwettingpropertiesbetweennucleusandsubstratesurface,andthesurfacestructureofcertaingeometricalscales,bothimposeeffectsontheheterogeneousnucleationproperties.Foranucleus-wettingsubstratesurface,heterogeneousnucleationispromotedbyahighercomplexityofthesurfacemorphology;butforanucleus-nonwettingsubstratesurface,heterogeneousnucleationisinhibitedbyahighercomplexityofthesurfacemorphology.
简介:TheheterogeneousnucleationbehaviorsofNH4ClcrystalonaroughchillingsurfaceofaluminumimmergedinNH4Cl-H2Osolutionwereexperimentallyanalyzedandtherelationshipbetweenthesurfaceroughnessandthenucleationsiteselectionbehaviorsonpolishedaluminumsubstratewasinvestigated,anditwasdiscoveredthatthenumberofnucleationsitesdecreasessignificantlywithdecreasingtheroughnessofthepolishedsubstrate.Furthernucleationexperimentswerecarriedoutonchemicallyetchedaluminumsubstratewithregularmicro-morphologyonitssurface.Ithasbeenshownthatboththemicro-morphologyandthewettabilityvarywiththesubstratesurfacepreparedbydifferentetchingprocess.Thepreparedsurfacewithstep-likestructureshasastrongwettabilitywithNH4Cl-70wt%H2OsolutionandthenucleationdensityofNH4Clontheitssurfacesissignificantlyhigherthanthatofthereferencesurfaces,whichshowsthatthegeometricalmorphologyfeatureshaveimportanteffectsonboththewettabilityandthenucleationbehaviors.
简介:Electronicsystemswithlargestretchabilityhavemanyapplications.Apreciselycontrolledbucklingstrategytoincreasethestretchabilityhasbeendemonstratedbycombininglithographicallypatternedsurfacebondingchemistryandabucklingprocess.Thebuckledgeometrywasassumedtohaveasinusoidalform,whichmayresultinerrorstodeterminethestrainsinthefilm.Atheoreticalmodelispresentedinthislettertostudythemechanicsofthistypeofthinfilm/substratesystembydiscardingtheass...
简介:构造沼泽地(CW)是包括沼泽地植被,土壤,和他们在对待废水帮助的联系微生物引起的集合利用自然系统的设计系统。由象强风炉子炉渣(BFS)那样的CW底层材料的铵氮(NH+4-N)的运动吸附,沸石,ceramsite,蛭石,石子,稻土壤,红土壤,和草地,用批实验和运动吸附等温线被调查。Freundlich和Lang-muir等温线能足够地预言NH+4-N吸附过程。NH+4-N的最大的吸附能力,从兰米尔等温线估计了,是评价:沸石(33333.33mgkg1)>草地(29274.01mgkg1)>BFS(5000mgkg1)>蛭石(3333.33mgkg1)>石子(769.23mgkg1)>稻土壤(588.24mgkg1)>红土壤(555.56mgkg1)>ceramsite(107.53mgkg1)。底层材料的一些性质包括体积密度,比重,水力的电导率,一致性系数(K60),弯曲系数(Cc),有机物,pH,可交换(或活跃)Cu,Fe,Zn和Mn,全部的Cu,和Fe,Mn,Zn,Cd,Pb和Ca,与NH+4-N的有的否定关联吸附。底层材料的另外的性质喜欢D10,D30和D60(分别地,10%,30%和60%基于积聚的频率粒子在通过筛的底层材料的粒子尺寸的直径)的粒子直径价值,阳离子交换能力(CEC),可交换(或活跃)Ca和Mg,和全部的K和Mg与NH+4-N有积极关联吸附。另外,象全部的Na一样的活跃K和Na与NH+4-N吸附有重要积极关联。这个信息将为为CW的合适的底层材料的选择是有用的。
简介:Tostudythemechanicalpropertiesofthefilm/substratestructure,thefiniteelementcodeABAQUSv6.9-1isadoptedtosimulatethetensilemechanicalbehaviorofthenanoscalethinfilmbondedtoasubstrate.Thebifurcationphenomenonofthestructureunderuniaxialtensionisfound:thesingle-neckdeformation,themultiple-neckdeformationandtheuniformdeformation.Thesubstrateandthefilmareregardedaspower-hardeningmaterialsobeyingtheJ2deformationtheory.Firstly,theinfluenceofmaterialhardeningmatchontensilebifurcationmodeisanalyzedunderperfectlywell-bondedinterfacecondition.Then,theeffectsofinterfacialstiffnessandothersuperficialdefectssurroundingtheimperfectiononbifurcationmodeareinvestigated.Itisconcludedthatunderthewell-bondedinterfacecondition,ifthestressofthesubstrateislargerthanthefilm,thefilmwilluniformlydeformwiththesubstrate;ifthestressofthesubstrateissmallerthanthefilm,thefilmwillformasingleneck,exceptthecasethataweakly-hardeningfilmisbondedtoasteeply-hardeningsubstratewhenmultipleneckscanbeformed.Withthedecreaseofinterfacialstiffness,theuniformdeformationmodecantransformintothemultiple-neckdeformationmode,andfurthertransformintothesingle-neckdeformationmode.Andotherdefectssurroundingtheimperfectioncaninfluencethewavelengthofdeformationandnecknumber.
简介:Themicro-characteristicsofthestreakymarksandthecorrespondingsubstratesurfaceofgalvannealed(GA)steelsheetshavebeeninvestigatedusingSEMandFIB.Thestreakymarkareaseemstohavemanycavities,similartocraters,whichscatterlightandmakethesurfaceappeardarkerwhencomparedwiththesurroundingnormalarea.Moreover,itisfoundthattheirregularityordifferenceinsteelgrainsizetendstoaffectthesurfacequalityoftheGAsteelsheets.Duringalloying,thediffusionspeedofZn-Feonthegrainboundaryisfasterthanthatatthecenterofthegrain,whichresultsintheselectiveformationofcrater-likemorphologyinthecoatingareawithlargersteelgrains.DuetothecleargrainboundaryofIFsteel,apparentstreakymarkswillbeformedonthecoatin,iftheIFsteelsurfaceconsistsofrainsofirreularsize.
简介:Thinfilm/substratematerialsystemshavebeenwidelyusedinvariousindustriessuchasaerospace,automotive,marineandelectronics.Oneexampleisthermalbarriercoatings(TBCs):TBCsareextensivelyappliedtometalliccomponentsongasturbineenginesinordertoprotectthemfromhighandprolongedheatloads,andtheyplayanessentialroleintheaircraftindustry.Anotherexampleislaminatedpolymermatrixcomposites(PMCs),reinforcedwithfiberssuchascarbon,glassoraramid:Thesematerialshavebeenextensivelyemployedinavarietyofapplicationsduetotheirsuperiorpropertiesandtheimprovingeaseandcost-effectivenessoffabricatingthem.Theevaluationofmechanicalpropertiesforthinfilm/substratematerialsystemsisimperativeformoreefficientuseofthesematerialsystemsandfurtherimprovements.
简介:Thisarticle,bycomparingthebasicconceptsofsubstrateandsoil,theircompositionofsubstanceandmethodsofmeasuringtheindexesofphysicalandchemicalproperties,analyzesandresearcheswaysofchoosingsubstrateforcultivationwithfacilities.Itindicatesthatthenormalphysicalandchemicalindexesofevaluatingasubstratearebulkdensity,totalporosity,non-capillaryporosity,ratioofbigporositytosmallporosity,thepHandtheelectricalconductivity(EC)valueofthesubstrate.By...
简介:Wehaveinvestigatedthephysicalproperties,includingthemorphology,texture,adhesionandchemicalquality,ofhigh-frequencychemicalvapourdepositeddiamondcoatingsonWC-6%Cosubstrates,whichwerepre-treatedbyatwo-stepetchingmethod.TheresultsindicatethattheincreasingCocontentfrom0.12to3.05%withintheetchingdepthof5μmcausedamorphologytransformationfromprismdiamondtospheruliticdiamond,andatexturetransformationfroma{111}orientationtoa{110}orientation.TheRamanspectrumshowsthatthespheruliticdiamondfilmcontainsmorenon-diamondphases(graphite,amorphouscarbonanddiamond-likecarbon,etc)andhaslowerchemicalqualitythandiamondfilmsonaWC-6%Cosubstrate.Thediamondcoatinggrainsizesbecameaboutfourtimessmallerwhenthedepositiontemperaturesonthesubstratesurfacewerereducedfrom1000to900℃.Comparedwithspheruliticdiamondfilms,theprismdiamondfilmsexhibitbetteradhesionontheWC-6%Cosubstrate.
简介:Geepilayersofdifferentthicknessesaregrownbymolecular-beamepitaxywithSbasasurfactantonSI(100)substrates,X-raydiffractionillustratesthattheseGethinfilmsarepartiallystrained.andthestrainsdecreasegraduallywithincreasingepilayerthickness,RamanspectrarevealadownwardshiftoftheGe-Gemodepeakastheepilayerthicknessincreases.Intheregionsofhighstrain,therelationshipbetweentheRamanshiftofthismodeandthestraininthepartiallyrelaxedsamplesisconsiderablydifferentfromthelinearrelationshipreportedbefore,whichismainlyattributedtothespatialconfinementeffectofphononsinananocrystal.
简介:Thisstudyconcernsatwo-dimensionalmodelandthecorrespondingvirtualcrackclosuretechnique(VCCT)implementedtosolvethegeneralboundaryvalueproblemsthatmayexplainwhyinterfacediscontinuityhaseffectsonthefracturebehaviorinthesuperconductor-substratesystem.Theinterfacialdiscontinuitycanbeclassifiedaccordingtothematerialproperties'continuityandtheirderivatives'continuityattheinterface.Fornonhomogeneoussuperconductorandsubstratespecimenswithvariousmaterialproperties,aVCCTmethodisdevelopedtocalculatetheirfracturebehavior.Furthermore,theeffectsofappliedmagneticfieldamplitudeandnonhomogeneousparametersareextensivelyandparametricallystudiedintwoactivationprocesses(zero-fieldcoolingandfieldcooling).Theintegrativeandcomputationalstudypresentedhereprovideafundamentalmechanisticunderstandingofthefracturemechanisminthesuperconductor-substratesystemandshedslightontherationaldesignofinterfacialcontinuity.
简介:Tetrahedralamorphoushydrogenatedcarbon(ta-C:H)filmsonSi(lO0)substrateswerepreparedbyusingamagnetic-field-filterplasmastreamdepositionsystem.Sampleswithdifferentratiosofsp^3-bondtosp^2-bondwereobtainedbychangingthebiasvoltageappliedtothesubstrates.Theellipsometricspectraofvariouscarbonfilmsinthephotonenergyrangeof1.9-5.4eVweremeasured.Therefractiveindexnandtherelativesp^3CratioofthesefilmswereobtainedbysimulatingtheirellipsometricspectrausingtheForouhi-BloomermodelandbyusingtheBruggemaneffectivemediumapproximation,respectively.Thehaemocompatibilityoftheseta-C:Hfilmswasanalysedbyobservationofplateletadhesionandmeasurementofkineticclottingtime.Theresultsshowthatthesp^3Cfractionisdependentonthesubstratebiasvoltage,andthehaemocompatibilityisdependentontheratioofsp^3-bondtosp^2-bond.Agoodhaemocompatibilitymaterialofta-C:Hfilmswithasuitablesp^3Cfractioncanbepreparedbychangingthesubstratebiasvoltage.
简介:Anewmethodforthedeterminationoftracecalciumbysolidsubstrate-roomtemperaturephosphorimetryisestablished.ItisbasedonthefactthatchromeazurolsazurolS-phenanthroline-NaCMC(CAS-phen-NaCMC)systemcanemitstrongandstableroomtemperaturephosphorescence(RTF)onthesolidsubstrateinthefilterpaper.Ca2+andphenanthrolinecanformcomplexionCa(phen)32+,whichwillformcomplex[Ca(phen)3(CAS)2]withCAS.Intheresult,thenumberofCASmoleculesineachspotincreased,causingsharpincreaseoftheRTPsignaloftheCAS-phen-NaCMCsystem.