简介：Ourobjectivesweretodevelopanewchemicalmethodforthepolymerizationofpyrrole.CuCl2dissolvedinC2H5OHsolventisprimarilyusedfortheinitiationpolymerizationofpyrrole.ThepolymerswithdifferentyieldandconductivitywereobtainedbyraringtheinitialconcentrationofCu2+.TheinitialconcentrationsofCu2+variedfrom1.2×10-4moleto6.48×10-3moleCu2+with2.16×10-2molepyrrole.Thepolypyrroleobtainedwascharacterizedwithelementalanalyzer,XPS,IRspectroscopy,Four-pointprobeandSEM.
简介：Thethree-phasesbehaviorinthequaternarystsemofn-dodecylpolyglucosideC12G1.46/1-butanol/cyclohexane/waterhasbeenstudiedat40℃intermsofthevariablesγandδ.Increasingδatconstantγcausesaphaseinversionfromanoil-in-watermicroemulsionincontactwithexcessoil(winsorIor2)toawater-in-oilmicroemulsionincontactwithexcesswater(winsorⅡor2)viaamiddle-phasemicroemulsionincontactwithexcessoilandwater(winsorⅢor3).Bytakingintoaccountthedifferentsolubilitiesofalkylpolyglucosideand1-butanolintheoilphase,thecompositionofthehydrophile-lipophilebalancedinterfacialfilminthemiddleofthethree-phasebodycanbecalculated.Theeffectsofdifferentoilsandaqueousmediaonthephasebehaviorandonthecompositionoftheinterfacialfilmandtheefficiencyforalkylpolyglucosidetomakeequalweightsofwaterandoiltoasinglephasewereinvestigated.Itwasfoundthattheoilmoleculeswithsmallmolecularvolumescanimprovethesolubilizingefficiencyofthesurfactanttoformsingle-phasemicroemulsion.Ininorganicsalt(NaCl)andacid(HCl)solutions,less1-butanolisneededthanthatinalkali(NaOH)solutiontoformmiddle-phasemicroemulsion.
简介：ＭａｓｓＹｉｅｌｄＤｉｓｔｒｉｂｕｔｉｏｎｏｆＴａｒｇｅｔＲｅｓｉｄｕｅｓｆｒｏｍＩｎｔｅｒａｃｔｉｏｎｏｆＩｒｏｎｗｉｔｈ１３５ＭｅＶ／ｕ１２ＣＩｏｎｓ￥ＱｉｎＺｈｉ；ＬｉＷｅｎｘｉｎ；ＺｈａｏＬｉｎ；ＷｅｎＷａｎｘ...
简介：Thesingle-shotspiralmagneticresonanceimaging(MRI)techniquewasimplementedandoptimizedonaBrukerBiospec47/30scanner.Thetechniqueincludesthepulsesequenceforgenerationanddetectionofthek-spaceMRIsignal(freeinductiondecay(FID)),andPC-basedprogramsforthedatagridandimagereconstruction.Thetemporalresolutionis70ms(14imagespersecond),whichconsistsofadataacquisitiontimeasshortas13.7ms,aspin-echotimeof13.6msandamagnetizationrecoverytimeof43ms.Thismakesitpossibletotakereal-timeimagesofmovingobjects.Thetechniqueisdemonstratedusingapendulum(tube)filledwithwater.
简介：对TATB及其系列衍生物进行了半经验分子轨道PM3和AM1计算,求得全优化几何构型和电子结构.结果发现各化合物分子中C-NO2键的Wiberg键级(WCN)均小于其他C-N或C-C键的键级.实验撞击感度h50%与WCN计算结果之间分别呈三阶或二阶多项式关系,相关系数r≥0.92.当WCN＜0.90时,该值对撞击感度影响甚微,表明属高感度炸药;而当WCN＞0.90时,撞击感度与分子中最小的C-NO2键级WCN呈显著的线性关系,WCN增大,撞击感度线性递减,符合判别感度相对大小的"最小键级原理".
简介：WereportonN-dopedp-typeZnOfilmswiththec-axisparalleltothesubstrate.ZnOfilmswerepreparedonana-Al2O3(0001)substratebysolid-sourcechemicalvapourdeposition(CVD),Zn(CH3COO)2.2H2OwasusedastheprecursorandCH3COONH4asthenitrogensource.Thegrowthtemperaturewasvariedfrom300℃to600℃,theas-grownZnOfilmdepositedat500℃showedp-typeconductionwithitsresistivityof42Ωcm,carrierdensity3.7×10^17cm^-3andHallmobility1.26cm^2V^-1.s^-1atroomtemperature,whicharethebestpropertiesforp-typeZnOdepositedbyCVD.Thep-typeZnOfilmpossessesatransmittanceofabout85%inthevisibleregionandabandgapof3.21eVatroomtemperature.
简介：Thetitlecomplexi-C4H9Co（salen）（Py）（Py=pyridine.salen=dianionofdisalicylideneethylenediamine）hasbeenfirstsynthesized.ItscrystalstructurehasbeendeterminedbyX-raydiffractionmethod.ThecrystsisaremonoclinicwithspacegroupP21/C.Theunitcellparametesarepresented.ThestructurehasbeenrefinedtoafinalRof0.038.
简介：定义在C^n中具有逐块光滑边界的有界域上光滑函数的一种积分表示，这种积分表示的特点是积分式中含有局部的全纯核，且含有可供任意选择的实参数p，2≤p<+∝，利用这个公式，我们可获得有界域上-↑a-方程的局部解和证明在含参数局部意义下存在一致估计。
简介：Tetrabutylammoniumorpotassiumsaltsoforganometalllicderivativesoflacunarypolyanion(RM)3P2W15O59^n-(RM=CpTi,CpZr,C4H7O2SnorC5H9O2Sn)havebeenpreparedandstructurallycharacterizedbyelementalanalysis,IR,UV-Vis,^1HNMRand^183WNMRspectroscopies.Thetitlecomplexesexhibitantitumoractivityinvitro.
简介：theAlternatingSegmentCrank-Nicolsonschemeforone-dimensionaldiffusionequationhasbeendevelopedin[1],andtheAlternatingBlockCrank-Nicolsonmethodfortwo-dimensionalproblemin[2].Themethodshavetheadvantagesofparallelcomputing,stabilityandgoodaccuracy.Inthispaperforthetwo-dimensionaldiffusionequation,thenetregionisdividedintobands,aspecialkindofblock.ThismethodiscalledthealternatingBandCrank-Nicolsonmethod.
简介：ThisisoneoftheapplicationsofPart(Ⅰ),inwhichtheangularstiffness,thelateralstiffnessandthecorrespondingstressdistributionsofC-shapedbellowswerecalculated.Thebellowswasdividedintoprotrudingsectionsandconcavesectionsfortheuseofthegeneralsolution(Ⅰ),butthecontinuityofthestressresultantsandthedeformationsateachjointofthesectionswereentirelysatisfied.Thepresentresultswerecomparedwiththoseoftheothertheoriesandexperiments,andarealsotestedbythenumericallyintegralmethod.Itisshownthatthegoverningequationandthegeneralsolution(I)areveryeffective.
简介：Thecrystalandmolecularstructuresof[(C3H7O)2PS2]2(CCDCNo.217201)weredeterminedbymeansofX-raycrystallography.ItcrystallizedinatriclinicsystemwithspacegroupP1^-andlatticeparametersa=0.82794(3)nm,b=0.84764(2)nm,c=0.85034(3)nm,α=97.78(3)°β=110.77(3)°,γ=94.95(3)°,V=0.54701(9)nm^3,Z=1.Inthismolecule,thetwodiisopropyldithiophosphategroups,[(C3H7O)2PS2]2,whichareparalleltoeachother,arelinkedbyanS--Sbondandthereexistinversioncentersinthemolecule,Inthestructure,theP=Sbondsinthetwodithiophosphateunitsaretrans-orientedtoeachother.
简介：Theoptimalconditionsforthecomplexationreactionofmeso-tetra(3-methoxy-4-hy-droxyphenyl)porphineT(3-M-4HP)Pwithplatinumandrhodiumarepresented.Beer’sLawisobeyedwhentheconcentrationofrhodiumisintherangeof0.45-1.15μg/25mL.Themolarabsorptivityofrhodiumwasfoundtobe1.99×106L·mol-1·cm-1at460nm.ThevalueofεPtwasfoundtobe6.28×105L·mol-1·cm-1bylinearregressionmethod.TheKcoefficientmethodandcompensatingcoefficientwereusedtodetermineplatinumandrhodiumsimultaneoulywithoutremovalormaskingoftheinterferentsinthesample.Theresultsforthedeterminationofplatinumandrhodiuminthemixedsolutionofplatinumandrhodiumaresatisfactory.
简介：<正>Foranyintegersa1,a2,a3,a4andcwitha1a2a3a40（modp）,thispapershowsthatthereexistsasolutionX=（x1,x2,x3,x4）∈Z4ofthecongruencea1x12+a2x22+a3x32+a4x42≡c（modp）suchthat‖X‖=max{|x1|,|x2|,|x3|,|x4|}《p1/2logp.
简介：ThehydrolysisofcephanoneinTritonX-100micelleandTritonX-100/n-C5H11OH/H2O(O/W)microemulsionwerestudiedbymeansofUV-Visabsorptionspectroscopy.Theresultsshowthatcomparedwithwater,TritonX-100micelleandTritonX-100/n-C5H11OH/H2O(O/W)microemulsioncaninhibitthehydrolysisofcephanone.TheinhibitioneffectsofTritonX-100micelleandTritonX-100/n-C5H11OH/H2O(O/W)microemulsiononthehydrolysisofcephanonearerelatedtothelocationofcephanoneintheinterphasesofTritonX-100micellesandTritonX-100/n-C5H11OH/H2O(O/W)microemulsiondroplets.
客服QQ：30444492琼网文【2021】1550-113号
增值电信业务经营许可证：琼B2-20210322
出版物经营许可证：新出发龙华出字第(2021)009号
广播电视节目制作经营许可证：(琼)字第00779号
版权所有 ©2002-2024 期刊网(www.qikanchina.com) 琼ICP备2021005105号
![Crystal Structure of Bis （0, O＇-diisopropyl dithiophosphate） ： [（<b style='color:red'>C</b>3H7O）2PS2]2](/image/thesis16 "Crystal Structure of Bis （0, O＇-diisopropyl dithiophosphate） ： [（<b style='color:red'>C</b>3H7O）2PS2]2")
