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422 个结果
  • 简介:SupposethatDisaboundeddomainwithapiecewiseC^1smoothboundaryinC^n.Letψ∈C^1+α(δD).ByusingtheHadamardprincipalvalueofthehigherordersingularintegralandsolidanglecoefficientmethodofpointsontheboundary,wegivethePlemeljformulaofthehigherordersingularintegralwiththeBoehner-Martinellikernel,whichhasintegraldensityψ.Moreover,bymeansofthePlemeljformulaandmethodsofcomplexpartialdifferentialequations,wediscussthecorrespondingCauehyboundaryvalueproblemwiththeBoehner-Martinellikernelonaclosedpiecewisesmoothmanifoldandobtainitsuniquebranchcomplexharmonicsolution.

  • 标签: 柯西边值问题 PLEMELJ公式 主值 双曲线 偏微分方程
  • 简介:Basedonthethermodynamictheory,anorthotropicdamageconstitutivemodelwasdevelopedtodescribethenonlinearmechanicalbehaviorofC/SiCcomposites.Thediferentnonlinearkinematicandisotropichardeningfunctionswereadoptedtodescribeaccuratelythedamageevolutionprocesses.Thedamagevariablesweredefinedwiththedamagedmodulusandtheinitialundamagedmodulusonenergyequivalenceprinciple.Theinitialorthotropyanddamagecouplingwerepresentedinthedamageyieldfunction.Tensileandin-planeshearloadingandunloadingtestswereperformed,andagoodagreementbetweenthemodelandtheexperimentalresultswasachieved.

  • 标签: 连续损伤力学 复合材料 SIC 分析基 损伤本构模型 正交各向异性
  • 简介:TheeffectofacidcomponentincludingvariousconventionalacidsandtungsticcompoundsonglucosehydrogenationoveraseriesofbinarycatalystsystemcontainingRu/Ccatalystwasinvestigated.TheresultsshowedthatHCl,H2SO4,H3BO3,H3PO4,andHNO3hadnegligibleeffect,whileallthetungsticcompoundsimposedinhibitingeffectsonthehydrogenationofglucoseoverRu/Ccatalyst,andthesuppressingeffectfollowedtheorderofH2WO4>HPW>WO3>AMT>HSiW.Thisorderisthesameastheorderofethyleneglycol(EG)yieldsintheone-potconversionofglucosetoEG,suggestingtheimportantroleofcompetitionbetweenglucosehydrogenationandretro-aldolcondensationincontrollingtheselectivityofEG.

  • 标签: 葡萄糖加氢 催化剂体系 钨化合物 钌/碳催化剂 抑制效果 醛醇缩合
  • 简介:一、促反应中的活化能非催化反应与催化反应,可以简单地利用下面所谓"热力学箱"反应式来示意:其中A,B是两种底物,E为。(AB)~+是在H.Eyring意义下的过渡状态。K_s,,K_K是相应反应的速度常数。假定反应是在某种溶液中进行的。反应式的第一行表示非催化反应,第二行表示首先形成一底物复合物EAB,接着通过状态E(AB)~+,最后以一个新的速度常数K_E发生反应到达终态E_+产物。这就是催化反应。两种反应途径所到达的终态相同,但是反应的活化能△F不同。如图1。

  • 标签: 中的应用 动力学中的 晶格模型
  • 简介:在水热条件下合成了ENi(en)2]6E(VO)12O6B18O19(OH)3].6H2O多钒硼酸盐,X射线衍射分析表明,该晶体属三方晶系,R-3空间群.测试了晶体的IR光谱和TG曲线,用循环伏安法详细研究了合成化合物的氧化还原性质及电子转移机理,结果表明该化合物具有两对氧化还原峰,其电子转移数分别为单电子和三电子.

  • 标签: 水热合成 晶体结构 多钒硼酸盐 簇合物 氧化还原性质
  • 简介:PREPARATIONOFN--BUTYLOXYCARBONYL-O ̄α-9-FLUORENYLMETHYLESTEROFASPARTICACID¥ZongJinHAN;ZhenKaiDINGandQiKaiZHANG(BeijingInstitu...

  • 标签: ACID PREP
  • 简介:Inthispaperwegivetheexactorderof丨x-xk丨丨lk(x)丨foranyfixednonnegativeintegerssandt,whichisn-s,n-slnnandn1-fors≤t-2,s=t-1ands≥t,respectively.

  • 标签: EXACT Chebyshev SUPPOSE TRIVIAL INTEGERS something
  • 简介:如果一个图的匹配多项式可以被一个路的匹配多项式整除,我们就称此路是该图的一个路因子,路因子在刻画图的匹配等价类,研究匹配唯一性方面有很重要的作用.本文得到了图T1,1.m与图Q(3,n)中有路因子的充分必要条件.

  • 标签: 匹配多项式 路因子 特征标
  • 简介:Thedevelopmentofthehydrogenelectrodeisvitalfortheapplicationofalkalinepolymerelectrolytefuelcells(APEFCs).Inthisstudy,aseriesofNi(OH)2decoratedNi/Ccatalysts(Ni(OH)2-Ni/C)werepreparedbyathree-stepelectrochemicaltreatmentofNi/C.TheexistenceofNi(OH)2wasdemonstratedbyX-rayphotoelectronspectroscopy(XPS),andthesurfacemolarratioofNi(OH)2/Niofthesampleswasestimatedviaanelectrochemicalmethod.TheHORcatalyticactivityofthecatalystswasevaluatedbyarotationdiskelectrode(RDE)method,anda'volcanoplot'wasestablishedbetweentheHORexchangecurrent(j0)andthesurfacemolarratioofNi(OH)2/Ni.Ontopofthe'volcano',thesurfacemolarratioofNi(OH)2/Niis1.1:1,thej0ofwhichwas6.8timesofthatofNi/C.ThestabilityofthesamplestowardHORwasevaluatedtobegood.OurstudyaddedasystematicexperimentalevidencetotheHORresearch,showingthattheHORcatalyticactivityofNicanbedeliberatelycontrolledviadecorationofNi(OH)2,whichmayhelpunderstandingtheHORmechanismonNi.

  • 标签: Hydrogen oxidation reaction FUEL CELLS Alkaline
  • 简介:基于双连续半群概念,引入一致双连续半群序列概念,借助Laplace变换和Trotter-Kato定理,考察双连续n次积分C余弦函数与C-预解式之间的关系,得到逼近定理的稳定性条件,进而得出双连续n次积分C余弦函数逼近定理.从而对Banach空间强连续半群逼近定理和双连续半群逼近定理进行了推广,为相应抽象的Cauchy问题提供了解决方案.

  • 标签: 双连续半群 一致双连续半群 n次积分C余弦函数 预解式 逼近定理
  • 简介:Twocompactandintense2.45GHzpermanentprotonsourcesandtheircorrespondinglowenergybeamtransport(LEBT)systemsweredevelopedsuccessfullyforChinaAcceleratorDrivenSub-criticalsystem(C-ADS)in2014,oneofwhichwasbuiltatIMP,LanzhouandtheotheratIHEP,Beijing.Bothprotonsourcescandeliverstable10mA/35keVprotonbeamsatCWmodetotheentrancesofthedownstreamRFQs.AsshowninFig.1,thebeamsextractedbya3-electrodeextractionsystemaretransportedbytheLEBTsystem,whichiscomposedof2identicalsolenoids,andintothe3.2or2.1MeVradio-frequencyquadrupole(RFQ).Inordertoensuresuperconductingcavitiescommissioningandprotection,anelectrostatic-chopperhasbeendesignedandinstalledintheLEBTlinethatcanchopthecwbeamFig.2Totalhydrogenionbeamcurrentversusinputpower.intoapulsedone.Theachievedfall/risetimeofthechopperislessthan20ns.

  • 标签: STATUS INTENSE PROTON
  • 简介:让一,b,c,r被修理积极整数以便一(2)+b(2)=c(r),min(一,b,c,r)>1和2转换了微小r。在这篇论文,我们证明那如果等价物到2(现代派4),b等价物到3(现代派4),c>3。10(37)并且r>7200,然后方程(x)+b(y)=c(z)仅仅有答案(x,y,z)=(2,2,r)。

  • 标签: 纯指数丢番图方程 数字解 正整数 确定性
  • 简介:CarbonsupportedPt(Pt/C)electrocatalystswerepreparedwithglucoseasprotectionagentandNaBH4asreductant.ThePtnanoparticlesdepositedoncarbonsupportpresentedreducedsizeandwelldispersityattributedtotheprotectioneffectofglucose.GlucoseabsorbedontheparticlesurfacewasreadilyremovedbywaterwashingwithoutleadingtoagglomerationofthePtnanoparticles.Theas-preparedPt/Celectrocatalystsshowedimprovedmassactivityformethanolelectrooxidationcomparedtothecatalystpreparedwithoutglucoseprotection.TheimprovedperformanceisattributedtothelargerelectrochemicalactivesurfaceareathusincreasedactivesitesonthePt/Celctrocatalystspreparedundertheprotectionofglucose.

  • 标签: 葡萄糖吸收 电催化剂 保护剂 甲醇 电活动 PT纳米粒子